Title | Efficient synthesis and facile functionalization of highly fluorescent spiro [pyrrol-pyran] |
Author | |
Corresponding Author | Wang, Wenjing; Zhang, Xuanjun |
Publication Years | 2019-12
|
DOI | |
Source Title | |
ISSN | 0143-7208
|
EISSN | 1873-3743
|
Volume | 171 |
Abstract | Decent fluorescent scaffolds with desirable property and extensibility play critical role in the development of fluorescent material science and chemical biology. This contribution describes an efficient multicomponent strategy to construct spirocyclic scaffold SPP (spiro[pyrrol-pyran]) with differing substituents under mild condition. Through one-pot reaction, arylacetylene decorated by varying electron donating group can efficiently react with tetracyanoethylene, and alcohol or primary amine, producing a series of color tunable fluorophores with large stokes shift (up to 190 nm) and high fluorescent quantum yield (up to 0.83). The SPP core shows good structural stability towards pH and optical radiation. The polymeric spiro derivative NO6 was further functionalized to construct energy-transfer probe for ratiometric sensing ONOO-. |
Keywords | |
URL | [Source Record] |
Indexed By | |
Language | English
|
SUSTech Authorship | Others
|
Funding Project | University of Macau[MYRG2016-00058-FHS]
; University of Macau[MYRG2017-00066-FHS]
|
WOS Research Area | Chemistry
; Engineering
; Materials Science
|
WOS Subject | Chemistry, Applied
; Engineering, Chemical
; Materials Science, Textiles
|
WOS Accession No | WOS:000484870700097
|
Publisher | |
EI Accession Number | 20193207284414
|
EI Keywords | Amines
; Energy transfer
; Scaffolds (biology)
; Stability
|
ESI Classification Code | Biomedical Engineering:461.1
; Light/Optics:741.1
; Organic Compounds:804.1
|
ESI Research Field | CHEMISTRY
|
Data Source | Web of Science
|
Citation statistics |
Cited Times [WOS]:2
|
Document Type | Journal Article |
Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/25070 |
Department | Department of Biomedical Engineering |
Affiliation | 1.Univ Macau, Fac Hlth Sci, Canc Ctr, Macau 999078, Peoples R China 2.Univ Macau, Fac Hlth Sci, Ctr Precis Med Res & Training, Macau 999078, Peoples R China 3.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 4.Southern Univ Sci & Technol, Dept Biomed Engn, Shenzhen 518055, Guangdong, Peoples R China |
Recommended Citation GB/T 7714 |
Tan, Jingyun,Wang, Chunfei,Lao, Hio Kuan,et al. Efficient synthesis and facile functionalization of highly fluorescent spiro [pyrrol-pyran][J]. DYES AND PIGMENTS,2019,171.
|
APA |
Tan, Jingyun.,Wang, Chunfei.,Lao, Hio Kuan.,Feng, Gang.,Li, Gang.,...&Zhang, Xuanjun.(2019).Efficient synthesis and facile functionalization of highly fluorescent spiro [pyrrol-pyran].DYES AND PIGMENTS,171.
|
MLA |
Tan, Jingyun,et al."Efficient synthesis and facile functionalization of highly fluorescent spiro [pyrrol-pyran]".DYES AND PIGMENTS 171(2019).
|
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File Name/Size | DocType | Version | Access | License | ||
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