| Title | Catalytic Asymmetric [3+2] Cycloaddition Reaction between Aurones and Isocyanoacetates: Access to Spiropyrrolines via Silver Catalysis |
| Author | |
| Corresponding Author | Shao, Pan-Lin; He, Yun |
| Publication Years | 2018-09-21
|
| DOI | |
| Source Title | |
| ISSN | 0022-3263
|
| Volume | 83Issue:18Pages:10995-11007 |
| Abstract | The first enantioselective formal [3 + 2] cycloaddition of aurone analogues with isocyanoacetates was developed via chiral Ag-complex catalysis. A variety of optically enriched spiro-l-pyrrolines were obtained in excellent yields, diastero- and enantioselectivities (up to 99% yield, >20:1 dr, >99% ee). This synthetic approach represents an extremely simple, efficient, and atom-economical method for spiro-l-pyrrolines synthesis. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | Corresponding
|
| Funding Project | National Natural Science Foundation of China[21402150]
; National Natural Science Foundation of China[21572027]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Organic
|
| WOS Accession No | WOS:000445713000032
|
| Publisher | |
| EI Accession Number | 20182905557963
|
| EI Keywords | Catalysis
; Cycloaddition
; Enantioselectivity
|
| ESI Classification Code | Physical Chemistry:801.4
; Chemical Reactions:802.2
|
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:32
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/27216 |
| Department | School of Innovation and Entrepreneurship |
| Affiliation | 1.Chongqing Univ, Sch Pharmaceut Sci, 55 Daxuecheng South Rd, Chongqing 401331, Peoples R China 2.Chongqing Univ, Chongqing Key Lab Nat Prod Synth & Drug Res, 55 Daxuecheng South Rd, Chongqing 401331, Peoples R China 3.Southern Univ Sci & Technol, Coll Innovat & Entrepreneurship, Shenzhen 518000, Peoples R China |
| Corresponding Author Affilication | School of Innovation and Entrepreneurship |
| Recommended Citation GB/T 7714 |
Wang, Zhi-Peng,Xiang, Sichuan,Shao, Pan-Lin,et al. Catalytic Asymmetric [3+2] Cycloaddition Reaction between Aurones and Isocyanoacetates: Access to Spiropyrrolines via Silver Catalysis[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(18):10995-11007.
|
| APA |
Wang, Zhi-Peng,Xiang, Sichuan,Shao, Pan-Lin,&He, Yun.(2018).Catalytic Asymmetric [3+2] Cycloaddition Reaction between Aurones and Isocyanoacetates: Access to Spiropyrrolines via Silver Catalysis.JOURNAL OF ORGANIC CHEMISTRY,83(18),10995-11007.
|
| MLA |
Wang, Zhi-Peng,et al."Catalytic Asymmetric [3+2] Cycloaddition Reaction between Aurones and Isocyanoacetates: Access to Spiropyrrolines via Silver Catalysis".JOURNAL OF ORGANIC CHEMISTRY 83.18(2018):10995-11007.
|
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acs.joc.8b01622.pdf（2685KB） | Restricted Access | -- | ||||
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