| Title | Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation |
| Author | |
| Corresponding Author | He, Chuan |
| Publication Years | 2022-06-01
|
| DOI | |
| Source Title | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| Volume | 61 |
| Abstract | Despite growing progress in the construction of chiral organosilicon compounds, the catalytic asymmetric synthesis of silicon-stereogenic silanols is less explored and remains a considerable challenge. Herein, we report the first enantioselective construction of silicon-stereogenic silanols by the catalytic asymmetric hydrolytic oxidation of dihydrosilanes. This practical procedure features ambient reaction conditions, high atom economy, good functional-group compatibility, and H-2 as the only by-product, and produces a wide range of valuable chiral silanols and bis-silanols in decent yields with excellent chemo- and stereoselectivity. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Natural Science Foundation of China[21901104,22122102,22101120]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
; Shenzhen Science and Technology Innovation Committee[JCYJ20190809142809370]
; Stable Support Plan Program of Shenzhen Natural Science Fund[20200925152450004]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000813666100001
|
| Publisher | |
| EI Accession Number | 20222512252091
|
| EI Keywords | Silicon
; Silicon compounds
|
| ESI Classification Code | Air Pollution Control:451.2
; Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3
; Chemical Agents and Basic Industrial Chemicals:803
|
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:10
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/347933 |
| Department | Shenzhen Grubbs Institute 理学院_化学系 |
| Affiliation | 1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Guangdong, Peoples R China |
| First Author Affilication | Shenzhen Grubbs Institute; Department of Chemistry |
| Corresponding Author Affilication | Shenzhen Grubbs Institute; Department of Chemistry |
| First Author's First Affilication | Shenzhen Grubbs Institute |
| Recommended Citation GB/T 7714 |
Yuan, Wei,Zhu, Xujiang,Xu, Yankun,et al. Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022,61.
|
| APA |
Yuan, Wei,Zhu, Xujiang,Xu, Yankun,&He, Chuan.(2022).Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,61.
|
| MLA |
Yuan, Wei,et al."Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 61(2022).
|
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