中文版 | English
Title

Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation

Author
Corresponding AuthorHe, Chuan
Publication Years
2022-06-01
DOI
Source Title
ISSN
1433-7851
EISSN
1521-3773
Volume61
Abstract
Despite growing progress in the construction of chiral organosilicon compounds, the catalytic asymmetric synthesis of silicon-stereogenic silanols is less explored and remains a considerable challenge. Herein, we report the first enantioselective construction of silicon-stereogenic silanols by the catalytic asymmetric hydrolytic oxidation of dihydrosilanes. This practical procedure features ambient reaction conditions, high atom economy, good functional-group compatibility, and H-2 as the only by-product, and produces a wide range of valuable chiral silanols and bis-silanols in decent yields with excellent chemo- and stereoselectivity.
Keywords
URL[Source Record]
Indexed By
SCI ; EI
Language
English
Important Publications
NI Journal Papers
SUSTech Authorship
First ; Corresponding
Funding Project
National Natural Science Foundation of China[21901104,22122102,22101120] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Shenzhen Science and Technology Innovation Committee[JCYJ20190809142809370] ; Stable Support Plan Program of Shenzhen Natural Science Fund[20200925152450004]
WOS Research Area
Chemistry
WOS Subject
Chemistry, Multidisciplinary
WOS Accession No
WOS:000813666100001
Publisher
EI Accession Number
20222512252091
EI Keywords
Silicon ; Silicon compounds
ESI Classification Code
Air Pollution Control:451.2 ; Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Chemical Agents and Basic Industrial Chemicals:803
ESI Research Field
CHEMISTRY
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:16
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/347933
DepartmentShenzhen Grubbs Institute
理学院_化学系
Affiliation
1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Guangdong, Peoples R China
First Author AffilicationShenzhen Grubbs Institute;  Department of Chemistry
Corresponding Author AffilicationShenzhen Grubbs Institute;  Department of Chemistry
First Author's First AffilicationShenzhen Grubbs Institute
Recommended Citation
GB/T 7714
Yuan, Wei,Zhu, Xujiang,Xu, Yankun,et al. Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022,61.
APA
Yuan, Wei,Zhu, Xujiang,Xu, Yankun,&He, Chuan.(2022).Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,61.
MLA
Yuan, Wei,et al."Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 61(2022).
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