中文版 | English
Title

Modulated luminescence of zero-dimensional bimetallic all-inorganic halide clusters

Author
Corresponding AuthorLiu, Xiaolin; Chen, Hong; Lin, Jia
Publication Years
2022-06-01
DOI
Source Title
ISSN
2052-1553
Volume9Pages:3728-3736
Abstract
Zero-dimensional (0D) metal halide clusters formed as isolated metal halide polyhedral structures show excellent optical properties and have great potential for various applications in optoelectronic devices. In this study, we reported a series of Rb8CuB(iii)(3)Cl-18 single crystals (SCs) constructed from Cu(i) and B(iii) (B = In, Tb, etc.) containing lead-free bimetallic halide clusters. Density functional theory calculations have been used to explore the thermodynamic stability of the expected bimetallic halide clusters, in which the ionic radius of B(iii) trivalent metal cations should be within the range of 0.74 to 0.99 angstrom in order to form a stable Rb8CuB(iii)(3)Cl-18 0D structure in line with the same structure configuration. By analyzing the effects of different B(iii) cations on the structural parameters and optical-physical properties, we found that the luminescence of SCs could be modulated by different B(iii) cations, while the luminescence originated from the charge transfer from Cu(i) ions to metal-chloride octahedra. This study reported the rational design of novel-structured Cu(i)-based inorganic lead-free metal halide materials, which paves the way for the exploration of new luminescent materials.
URL[Source Record]
Indexed By
SCI ; EI
Language
English
SUSTech Authorship
Corresponding
Funding Project
National Natural Science Foundation of China[12174246,61875119] ; Science and Technology Commission of Shanghai Municipality[21010501300]
WOS Research Area
Chemistry
WOS Subject
Chemistry, Inorganic & Nuclear
WOS Accession No
WOS:000815204000001
Publisher
EI Accession Number
20222712307308
EI Keywords
Charge transfer ; Chlorine compounds ; Copper compounds ; Density functional theory ; Lead compounds ; Metal halides ; Metals ; Optical properties ; Optoelectronic devices ; Perovskite ; Positive ions ; Rubidium compounds ; Thermodynamic stability
ESI Classification Code
Minerals:482.2 ; Thermodynamics:641.1 ; Light/Optics:741.1 ; Optical Devices and Systems:741.3 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Probability Theory:922.1 ; Atomic and Molecular Physics:931.3 ; Quantum Theory; Quantum Mechanics:931.4
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:2
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/347937
DepartmentSchool of Environmental Science and Engineering
Affiliation
1.Shanghai Univ Elect Power, Dept Phys, Shanghai 200090, Peoples R China
2.Southern Univ Sci & Technol, Sch Environm Sci & Engn,State Environm Protect Ke, Guangdong Prov Key Lab Soil & Groundwater Pollut, Shenzhen Key Lab Interfacial Sci & Engn Mat, Shenzhen 518055, Peoples R China
Corresponding Author AffilicationSchool of Environmental Science and Engineering
Recommended Citation
GB/T 7714
Zhang, Chao,Feng, Xuezhen,Song, Qilin,et al. Modulated luminescence of zero-dimensional bimetallic all-inorganic halide clusters[J]. Inorganic Chemistry Frontiers,2022,9:3728-3736.
APA
Zhang, Chao.,Feng, Xuezhen.,Song, Qilin.,Zhou, Chaocheng.,Peng, Lin.,...&Lin, Jia.(2022).Modulated luminescence of zero-dimensional bimetallic all-inorganic halide clusters.Inorganic Chemistry Frontiers,9,3728-3736.
MLA
Zhang, Chao,et al."Modulated luminescence of zero-dimensional bimetallic all-inorganic halide clusters".Inorganic Chemistry Frontiers 9(2022):3728-3736.
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