| Title | Highly efficient and enantioselective synthesis of chiral lactones via Ir-catalysed asymmetric hydrogenation of ketoesters |
| Author | |
| Corresponding Author | Chen, Gen-Qiang; Zhang, Xumu |
| Publication Years | 2022-06-01
|
| DOI | |
| Source Title | |
| ISSN | 1359-7345
|
| EISSN | 1364-548X
|
| Volume | 58Pages:8408-8411 |
| Abstract | Owing to the biological significance and great synthetic value of chiral lactones and their derivatives, increasing attention has been paid to developing effective synthetic methods for chiral lactones. We herein report an efficient asymmetric hydrogenation of benzo-fused ketoesters, gamma-ketoesters and biaryl-bridged ketoesters catalyzed by chiral iridium complexes bearing ferrocene-based chiral ligands, furnishing a series of chiral lactones in superb yields and excellent enantioselectivities (up to 99% yields and up to 99% ee). |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
|
| SUSTech Authorship | Corresponding
|
| Funding Project | National Natural Science Foundation of China["21901107","22171129"]
; Shenzhen Bay Laboratory[SZBL2019062801006]
; Shenzhen Science and Technology Innovation Committee["JCYJ20210324104202007","KQTD2015071710315717"]
; Key-Area Research and Development Program of Guangdong Province["2021B1111110001","2020B010188001"]
; Stable Support Plan Program of Shenzhen Natural Science Fund[20200925161222002]
; Innovative Team of Universities in Guangdong Province[2020KCXTD016]
; Guangdong Basic and Applied Basic Research Foundation[2022B1515020055]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000821433100001
|
| Publisher | |
| EI Accession Number | 20223412623199
|
| EI Keywords | Catalysis
; Esters
; Hydrogenation
; Iridium compounds
; Iron compounds
; Ligands
; Organometallics
|
| ESI Classification Code | Physical Chemistry:801.4
; Chemical Reactions:802.2
; Organic Compounds:804.1
|
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/355869 |
| Department | Department of Chemistry 前沿与交叉科学研究院 |
| Affiliation | 1.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, 1088 Xueyuan Rd, Shenzhen 518055, Peoples R China 3.Shenzhen Bay Lab, Shenzhen 518132, Peoples R China 4.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Dept Chem, 1088 Xueyuan Rd, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Chemistry |
| Corresponding Author Affilication | Department of Chemistry; Academy for Advanced Interdisciplinary Studies |
| Recommended Citation GB/T 7714 |
Song, Jingyuan,Yin, Congcong,Zhang, Yao,et al. Highly efficient and enantioselective synthesis of chiral lactones via Ir-catalysed asymmetric hydrogenation of ketoesters[J]. CHEMICAL COMMUNICATIONS,2022,58:8408-8411.
|
| APA |
Song, Jingyuan.,Yin, Congcong.,Zhang, Yao.,Shi, Yongjie.,Li, Yingjun.,...&Zhang, Xumu.(2022).Highly efficient and enantioselective synthesis of chiral lactones via Ir-catalysed asymmetric hydrogenation of ketoesters.CHEMICAL COMMUNICATIONS,58,8408-8411.
|
| MLA |
Song, Jingyuan,et al."Highly efficient and enantioselective synthesis of chiral lactones via Ir-catalysed asymmetric hydrogenation of ketoesters".CHEMICAL COMMUNICATIONS 58(2022):8408-8411.
|
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
;
Edit Comment