中文版 | English
Title

Ancillary ligand-regulated Ti(iv)-based metallocalixarene coordination cages for photocatalytic H-2 evolution

Author
Corresponding AuthorXu, Cong-Qiao; Liu, Chao
Joint first authorTian, Yi-Qi; Cui, Yun-Shu
Publication Years
2022-07-15
DOI
Source Title
ISSN
1359-7345
EISSN
1364-548X
Volume58Issue:64Pages:9034-9037
Abstract

High-valence Ti(iv)-based metallocalixarene coordination cages that are linked by oriented ancillary ligands are unknown so far. Herein, the first family of tunable calixarene-based coordination cages of Ti(iv) with a framework formula [Ti-12((OPr)-Pr-i)(12)(TBC[4])(6)L-6] have been assembled from six {Ti-2((OPr)-Pr-i)(2)(TBC[4])}(2+) nodes and six pyridinedicarboxylic ligands. Furthermore, the {Ti12L6} cage showed strong photocatalytic H-2 evolution activity, and DFT studies were performed to explore its electronic structure.

URL[Source Record]
Indexed By
SCI ; EI
Language
English
Important Publications
NI Journal Papers
SUSTech Authorship
Corresponding
Funding Project
National Natural Science Foundation of China[
WOS Research Area
Chemistry
WOS Subject
Chemistry, Multidisciplinary
WOS Accession No
WOS:000829455500001
Publisher
EI Accession Number
20223112529646
EI Keywords
Electronic Structure ; Ligands ; Phenols ; Photocatalytic Activity
ESI Classification Code
Physical Chemistry:801.4 ; Organic Compounds:804.1
ESI Research Field
CHEMISTRY
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:2
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/359486
DepartmentDepartment of Chemistry
Affiliation
1.Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Chem Power Sources, Changsha 410083, Hunan, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
3.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
4.Tsinghua Univ, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Beijing 100084, Peoples R China
Corresponding Author AffilicationDepartment of Chemistry
Recommended Citation
GB/T 7714
Tian, Yi-Qi,Cui, Yun-Shu,Zhu, Jia-Hui,et al. Ancillary ligand-regulated Ti(iv)-based metallocalixarene coordination cages for photocatalytic H-2 evolution[J]. CHEMICAL COMMUNICATIONS,2022,58(64):9034-9037.
APA
Tian, Yi-Qi.,Cui, Yun-Shu.,Zhu, Jia-Hui.,Xu, Cong-Qiao.,Yi, Xiao-Yi.,...&Liu, Chao.(2022).Ancillary ligand-regulated Ti(iv)-based metallocalixarene coordination cages for photocatalytic H-2 evolution.CHEMICAL COMMUNICATIONS,58(64),9034-9037.
MLA
Tian, Yi-Qi,et al."Ancillary ligand-regulated Ti(iv)-based metallocalixarene coordination cages for photocatalytic H-2 evolution".CHEMICAL COMMUNICATIONS 58.64(2022):9034-9037.
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