Title | Ancillary ligand-regulated Ti(iv)-based metallocalixarene coordination cages for photocatalytic H-2 evolution |
Author | |
Corresponding Author | Xu, Cong-Qiao; Liu, Chao |
Joint first author | Tian, Yi-Qi; Cui, Yun-Shu |
Publication Years | 2022-07-15
|
DOI | |
Source Title | |
ISSN | 1359-7345
|
EISSN | 1364-548X
|
Volume | 58Issue:64Pages:9034-9037 |
Abstract | High-valence Ti(iv)-based metallocalixarene coordination cages that are linked by oriented ancillary ligands are unknown so far. Herein, the first family of tunable calixarene-based coordination cages of Ti(iv) with a framework formula [Ti-12((OPr)-Pr-i)(12)(TBC[4])(6)L-6] have been assembled from six {Ti-2((OPr)-Pr-i)(2)(TBC[4])}(2+) nodes and six pyridinedicarboxylic ligands. Furthermore, the {Ti12L6} cage showed strong photocatalytic H-2 evolution activity, and DFT studies were performed to explore its electronic structure. |
URL | [Source Record] |
Indexed By | |
Language | English
|
Important Publications | NI Journal Papers
|
SUSTech Authorship | Corresponding
|
Funding Project | National Natural Science Foundation of China[
|
WOS Research Area | Chemistry
|
WOS Subject | Chemistry, Multidisciplinary
|
WOS Accession No | WOS:000829455500001
|
Publisher | |
EI Accession Number | 20223112529646
|
EI Keywords | Electronic Structure
; Ligands
; Phenols
; Photocatalytic Activity
|
ESI Classification Code | Physical Chemistry:801.4
; Organic Compounds:804.1
|
ESI Research Field | CHEMISTRY
|
Data Source | Web of Science
|
Citation statistics |
Cited Times [WOS]:2
|
Document Type | Journal Article |
Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/359486 |
Department | Department of Chemistry |
Affiliation | 1.Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Chem Power Sources, Changsha 410083, Hunan, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 3.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 4.Tsinghua Univ, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Beijing 100084, Peoples R China |
Corresponding Author Affilication | Department of Chemistry |
Recommended Citation GB/T 7714 |
Tian, Yi-Qi,Cui, Yun-Shu,Zhu, Jia-Hui,et al. Ancillary ligand-regulated Ti(iv)-based metallocalixarene coordination cages for photocatalytic H-2 evolution[J]. CHEMICAL COMMUNICATIONS,2022,58(64):9034-9037.
|
APA |
Tian, Yi-Qi.,Cui, Yun-Shu.,Zhu, Jia-Hui.,Xu, Cong-Qiao.,Yi, Xiao-Yi.,...&Liu, Chao.(2022).Ancillary ligand-regulated Ti(iv)-based metallocalixarene coordination cages for photocatalytic H-2 evolution.CHEMICAL COMMUNICATIONS,58(64),9034-9037.
|
MLA |
Tian, Yi-Qi,et al."Ancillary ligand-regulated Ti(iv)-based metallocalixarene coordination cages for photocatalytic H-2 evolution".CHEMICAL COMMUNICATIONS 58.64(2022):9034-9037.
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