| Title | A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability |
| Author | |
| Corresponding Author | Ye, Qing |
| Publication Years | 2022-07-01
|
| DOI | |
| Source Title | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| Volume | 61 |
| Abstract | Herein, we report the facile synthesis of a three-dimensional (3D) inorganic analogue of 9,10-diazido-9,10-dihydrodiboraantracene, which turned out to be a monomer in both the solid and solution state, and thermally stable up to 230 degrees C, representing a rare example of azido borane with boosted Lewis acidity and stability in one. Apart from the classical acid-base and Staudinger reactions, E-H bond activation (E=B, Si, Ge) was investigated. While the reaction with B-H (9-borabicyclo[3.3.1]nonane) led directly to the 1,1-addition on N-alpha upon N-2 elimination, the Si-H (Et3SiH, PhMe2SiH) activation proceeded stepwise via 1,2-addition, with the key intermediates 5(int) and 6(int) being isolated and characterized. In contrast, the cooperative Ge-H was reversible and stayed at the 1,2-addition step. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | NSFC[22071095]
; National Young Talents Program, Technology Innovation Commission of Shenzhen Municipality[20200925152822004]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000832578800001
|
| Publisher | |
| EI Accession Number | 20223112525092
|
| EI Keywords | Reaction intermediates
; Silicon
; Silicon compounds
|
| ESI Classification Code | Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3
; Chemical Reactions:802.2
; Chemical Products Generally:804
|
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:4
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/365007 |
| Department | Department of Chemistry |
| Affiliation | 1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Clear Water Bay, Hong Kong, Peoples R China 3.Julius Maximilians Univ Wurzburg, Inst Inorgan Chem, D-97074 Wurzburg, Germany 4.Julius Maximilians Univ Wurzburg, Inst Sustainable Chem & Catalysis Boron, D-97074 Wurzburg, Germany |
| First Author Affilication | Department of Chemistry |
| Corresponding Author Affilication | Department of Chemistry |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Zhang, Chonghe,Liu, Xiaocui,Wang, Junyi,et al. A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022,61.
|
| APA |
Zhang, Chonghe,Liu, Xiaocui,Wang, Junyi,&Ye, Qing.(2022).A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,61.
|
| MLA |
Zhang, Chonghe,et al."A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 61(2022).
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