| Title | An Isolable Phosphaborene Stabilized by an Intramolecular Lewis Base |
| Author | |
| Corresponding Author | Liu, Liu Leo |
| Publication Years | 2022-08-01
|
| DOI | |
| Source Title | |
| ISSN | 1434-1948
|
| EISSN | 1099-0682
|
| Abstract | Phosphaborenes are P/B analogs of alkynes. Herein, we describe the isolation of a phosphaborene stabilized by an intramolecular Lewis base. This species is achieved via the installation of the phosphaborene with a sterically encumbering phosphino substituent. Although this species features an aromatic P2B three-membered ring, the ring strain allows the hemi-labile behavior of the P-B donor-acceptor bond, thereby exhibiting frustrated Lewis pair reactivity. Our finding paves the way for further exploration of the reactivity patterns of monomeric phosphaborenes. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Natural Science Foundation of China[22101114]
; Guangdong Basic and Applied Basic Research Foundation[2022A1515011717]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
; China Postdoctoral Science Foundation[2021M691420]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Inorganic & Nuclear
|
| WOS Accession No | WOS:000836210200001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:2
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/375574 |
| Department | Department of Chemistry 深圳格拉布斯研究院 |
| Affiliation | 1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute; Southern University of Science and Technology |
| Corresponding Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute; Southern University of Science and Technology |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Li, Jiancheng,Mei, Yanbo,Liu, Liu Leo. An Isolable Phosphaborene Stabilized by an Intramolecular Lewis Base[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2022.
|
| APA |
Li, Jiancheng,Mei, Yanbo,&Liu, Liu Leo.(2022).An Isolable Phosphaborene Stabilized by an Intramolecular Lewis Base.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY.
|
| MLA |
Li, Jiancheng,et al."An Isolable Phosphaborene Stabilized by an Intramolecular Lewis Base".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2022).
|
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