| Title | One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne |
| Author | |
| Corresponding Author | Zhang, Hong; Xia, Haiping |
| Publication Years | 2022-08-01
|
| DOI | |
| Source Title | |
| ISSN | 0947-6539
|
| EISSN | 1521-3765
|
| Abstract | A novel one-pot reaction producing a metal vinylidene structure in a five-membered ring by cyclization of a multiyne has been achieved. The ring strain and the high stability of the cyclic metal vinylidene complexes have been analyzed experimentally and computationally. The metal vinylidene unit in a fused-ring complex is unreactive to both nucleophiles and electrophiles. It reacts however at the nearby carbonyl group achieving the unprecedented conversion of metal tributing factors for the aromaticity-driven process has been studied by DFT calculations. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | Corresponding
|
| Funding Project | National Natural Science Foundation of China["21931002","21871225","22171234"]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000838162100001
|
| Publisher | |
| EI Accession Number | 20223312573810
|
| EI Keywords | Cyclization
|
| ESI Classification Code | Chemical Reactions:802.2
|
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:1
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/382295 |
| Department | Department of Chemistry 深圳格拉布斯研究院 |
| Affiliation | 1.Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 2.Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat iChEM, Xiamen 361005, Peoples R China 3.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute |
| Corresponding Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute |
| Recommended Citation GB/T 7714 |
Huang, Fanping,Yan, Zhewei,Zheng, Xuejuan,et al. One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne[J]. CHEMISTRY-A EUROPEAN JOURNAL,2022.
|
| APA |
Huang, Fanping,Yan, Zhewei,Zheng, Xuejuan,Cai, Yapeng,Zhang, Hong,&Xia, Haiping.(2022).One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne.CHEMISTRY-A EUROPEAN JOURNAL.
|
| MLA |
Huang, Fanping,et al."One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne".CHEMISTRY-A EUROPEAN JOURNAL (2022).
|
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