Title | “Breathing” organic cation to stabilize multiple structures in low-dimensional Ge-, Sn-, and Pb-based hybrid iodide perovskites |
Author | |
Corresponding Author | Mao,Lingling |
Publication Years | 2022
|
DOI | |
Source Title | |
EISSN | 2052-1553
|
Abstract | Low-dimensional hybrid inorganic-organic perovskites are excellent candidates for stable optoelectronic devices. The dimensionality of these perovskites depends largely on the organic and inorganic compositions, as well as the synthetic conditions. Here, we report five new hybrid iodides, (ETU)GeI, (ETU)GeI, (ETU)SnI, (ETU)PbI, and (ETU)PbI using only one type of organic cation, namely, S-(2-aminoethyl)isothiouronium (ETU). (ETU)GeI and (ETU)SnI belong to the (110)-oriented structure-type with “3 × 3” sawtooth corrugated layers and crystallize in a structure with the orthorhombic space group Pbca. (ETU)GeI crystallizes in a structure with the triclinic space group P1̄, featuring a 2D layered structure with combinations of corner, edge, and face-sharing [GeI] octahedra. For the Pb-based series, (ETU)PbI has the conventional (100) - oriented 2D type whereas (ETU)PbI has a unique 0D structure. Remarkably, the unstable 2D orange-phase (ETU)PbI transforms to a stable 0D yellow phase (ETU)PbI, accompanied by the reduction of the C-S-C angle of the organic cation ETU. The optical band gaps are largely regulated by the diverse types of structure and are in the range of 1.8 eV to 2.8 eV. (ETU)SnI is the only material showing notable photoluminescence at room-temperature. Our work showcases the flexibility of the organic cation in determining the structural dimensionality and provides a new strategy in generating new hybrid materials. |
URL | [Source Record] |
Indexed By | |
Language | English
|
SUSTech Authorship | First
; Corresponding
|
WOS Accession No | WOS:000839580500001
|
EI Accession Number | 20223412622144
|
EI Keywords | Energy gap
; Germanium compounds
; Hybrid materials
; Optoelectronic devices
; Perovskite
; Positive ions
; Tin compounds
|
ESI Classification Code | Minerals:482.2
; Optical Devices and Systems:741.3
|
Scopus EID | 2-s2.0-85136298265
|
Data Source | Scopus
|
Citation statistics |
Cited Times [WOS]:3
|
Document Type | Journal Article |
Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/395629 |
Department | Department of Chemistry |
Affiliation | 1.Department of Chemistry,Southern University of Science and Technology Shenzhen,Guangdong,518055,China 2.Materials Research Laboratory and Materials Department,University of California,Santa Barbara,93106,United States |
First Author Affilication | Department of Chemistry |
Corresponding Author Affilication | Department of Chemistry |
First Author's First Affilication | Department of Chemistry |
Recommended Citation GB/T 7714 |
Chen,Congcong,Morgan,Emily E.,Liu,Yang,等. “Breathing” organic cation to stabilize multiple structures in low-dimensional Ge-, Sn-, and Pb-based hybrid iodide perovskites[J]. Inorganic Chemistry Frontiers,2022.
|
APA |
Chen,Congcong,Morgan,Emily E.,Liu,Yang,Chen,Jian,Seshadri,Ram,&Mao,Lingling.(2022).“Breathing” organic cation to stabilize multiple structures in low-dimensional Ge-, Sn-, and Pb-based hybrid iodide perovskites.Inorganic Chemistry Frontiers.
|
MLA |
Chen,Congcong,et al."“Breathing” organic cation to stabilize multiple structures in low-dimensional Ge-, Sn-, and Pb-based hybrid iodide perovskites".Inorganic Chemistry Frontiers (2022).
|
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