中文版 | English
Title

A Room-Temperature Stable Distonic Radical Cation

Author
Corresponding AuthorGrützmacher,Hansjörg
Publication Years
2020
DOI
Source Title
ISSN
0935-9648
EISSN
1521-4095
Volume132Issue:52Pages:24038-24043
Abstract
Distonic radical cations (DRCs) with spatially separated charge and radical sites have, so far, largely been observed by gas-phase mass spectrometry and/or matrix isolation spectroscopy work. Herein, we disclose the isolation of a crystalline dicarbondiphosphide-based /3-distonic radical cati on sa It 3 (BARF) (BARF=[B(3,5-(CF)CH))D sta- ble at room temperature and formed by a one-electron- oxidation-induced intramolecular skeletal rearrangement re- action. Such a species has been validated by electron para- magnetic resonance (EPR) spectroscopy, single-crystal X-ray diffraction, UV/Vis spectroscopy and density functional theory (DFT) calculations Compound 3(BARF) exhibits a large majority of spin density at a two-coordinate phosphorus atom (0.74 a.u.) and a cationic charge located predominantly at the four-coordinate phosphorus atom (1.53 a.u.), which are sepa- rated by one carbon atom. This species represents an isolable entity of a phosphorus radical cation that is the closest to a genuine phosphorus DRC to date.
Keywords
URL[Source Record]
Indexed By
Language
English
Important Publications
NI Journal Papers
SUSTech Authorship
Others
EI Accession Number
20223412618038
EI Keywords
Atoms ; Density functional theory ; Electron spin resonance spectroscopy ; Mass spectrometry ; Positive ions ; Room temperature ; Single crystals ; Ultraviolet visible spectroscopy
ESI Classification Code
Thermodynamics:641.1 ; Chemistry:801 ; Chemical Products Generally:804 ; Probability Theory:922.1 ; Atomic and Molecular Physics:931.3 ; Quantum Theory; Quantum Mechanics:931.4 ; Crystalline Solids:933.1
ESI Research Field
MATERIALS SCIENCE
Scopus EID
2-s2.0-85136194821
Data Source
Scopus
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/395655
DepartmentDepartment of Chemistry
深圳格拉布斯研究院
Affiliation
1.College of Chemistry and Materials Science,Jinan University Guangzhou,510632,China
2.Shenzhen Grubbs Institute and Department of Chemistry,Southern University of Science and Technology Shenzhen,Shenzhen,518055,China
3.Lehn Institute of Functional Materials (LIFM),School of Chemistry,Sun Yat-Sen University Guangzhou,510275,China
4.State Key Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin,30071,China
5.Department of Chemistry and Applied Biosciences,ETH Zfrich Vladimir-Prelog-Weg 1,Zfrich,8093,Switzerland
Recommended Citation
GB/T 7714
Chen,Xiaodan,Liu,Liu Leo,Liu,Shihua,et al. A Room-Temperature Stable Distonic Radical Cation[J]. ADVANCED MATERIALS,2020,132(52):24038-24043.
APA
Chen,Xiaodan,Liu,Liu Leo,Liu,Shihua,Grützmacher,Hansjörg,&Li,Zhongshu.(2020).A Room-Temperature Stable Distonic Radical Cation.ADVANCED MATERIALS,132(52),24038-24043.
MLA
Chen,Xiaodan,et al."A Room-Temperature Stable Distonic Radical Cation".ADVANCED MATERIALS 132.52(2020):24038-24043.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Export to Excel
Export to Csv
Altmetrics Score
Google Scholar
Similar articles in Google Scholar
[Chen,Xiaodan]'s Articles
[Liu,Liu Leo]'s Articles
[Liu,Shihua]'s Articles
Baidu Scholar
Similar articles in Baidu Scholar
[Chen,Xiaodan]'s Articles
[Liu,Liu Leo]'s Articles
[Liu,Shihua]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Chen,Xiaodan]'s Articles
[Liu,Liu Leo]'s Articles
[Liu,Shihua]'s Articles
Terms of Use
No data!
Social Bookmark/Share
No comment.

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.