中文版 | English
Title

Enantioselective Silylation of Aliphatic C-H Bonds for the Synthesis of Silicon-Stereogenic Dihydrobenzosiloles

Author
Corresponding AuthorHe,Chuan
Publication Years
2020
DOI
Source Title
ISSN
0935-9648
EISSN
1521-4095
Volume132Issue:49Pages:22401-22406
Abstract
A rhodium(l)-catalyzed enantioselective silylation of aliphatic C-H bonds for the synthesis of silicon-stereogenic dihydrobenzosiloles is demonstrated. This reaction involves a highly enantioselective intramolecular C(sp)-H silylation of dihydrosilanes, followed by a stereospecific intermolecular al- kene hydrosilylation leading to the asymmetrically tetrasub- stituted silanes A wide range of dihydrosilanes and alkenes displaying various functional groups are compatible with this process, giving access to a variety of highly functionalized si- licon-stereogenic dihydrobenzosiloles in good to excellent yields and enantioselectivities.
Keywords
URL[Source Record]
Indexed By
Language
English
Important Publications
NI Journal Papers
SUSTech Authorship
First ; Corresponding
EI Accession Number
20223412618107
EI Keywords
Catalysis ; Enantioselectivity ; Silanes ; Silicon
ESI Classification Code
Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Organic Compounds:804.1
ESI Research Field
MATERIALS SCIENCE
Scopus EID
2-s2.0-85136188801
Data Source
Scopus
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/395656
DepartmentDepartment of Chemistry
深圳格拉布斯研究院
Affiliation
Shenzhen Grubbs Institute and Department of Chemistry,Guangdong Provincial Key Laboratory of Catalysis,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
First Author AffilicationDepartment of Chemistry;  Shenzhen Grubbs Institute
Corresponding Author AffilicationDepartment of Chemistry;  Shenzhen Grubbs Institute
First Author's First AffilicationDepartment of Chemistry;  Shenzhen Grubbs Institute
Recommended Citation
GB/T 7714
Yang,Bo,Yang,Wu,Guo,Yonghong,et al. Enantioselective Silylation of Aliphatic C-H Bonds for the Synthesis of Silicon-Stereogenic Dihydrobenzosiloles[J]. ADVANCED MATERIALS,2020,132(49):22401-22406.
APA
Yang,Bo,Yang,Wu,Guo,Yonghong,You,Lijun,&He,Chuan.(2020).Enantioselective Silylation of Aliphatic C-H Bonds for the Synthesis of Silicon-Stereogenic Dihydrobenzosiloles.ADVANCED MATERIALS,132(49),22401-22406.
MLA
Yang,Bo,et al."Enantioselective Silylation of Aliphatic C-H Bonds for the Synthesis of Silicon-Stereogenic Dihydrobenzosiloles".ADVANCED MATERIALS 132.49(2020):22401-22406.
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