Multi-component surface engineering of Na3V2(PO4)(2)O2F for low-temperature (-40 degrees C) sodium-ion batteries

Zheng, Kunxiong1; Xu, Shitan1; Yao, Yu2; Chen, Dong1; Liu, Lin1; Xu, Chen3; Feng, Yuezhan4; Rui, Xianhong1; Yu, Yan2

2022-08-01

10.1039/d2cc03281c

CHEMICAL COMMUNICATIONS   Impact Factor & Quartile

1359-7345

1364-548X

A functional Na3V2(PO4)(2)O2F (NVPOF) cathode with a multi-component (Na3V(PO4)(2), V2O3, and reduced graphene oxide) surface coating is developed via a facile hydrothermal reaction followed by calcination, and exhibits high reversible capability, and long-term cycling stability even at a low temperature of -40 degrees C. It is demonstrated that the multi-component-coating layer can significantly accelerate the e(-)/Na+ transport and reduce the interfacial resistance at low temperature. This work provides a novel strategy to boost the kinetics and stability of electrode materials for low-temperature sodium ion batteries.

SCI

English

NI Journal Papers

Others

National Natural Science Foundation of China["51925207","U1910210","52161145101","51872277","51972067","51902062","52002083"] ; ``Transformational Technologies for Clean Energy and Demonstration'' Strategic Priority Research Program of Chinese Academy of Sciences[XDA21000000] ; Yulin University[2021002] ; Dalian National Laboratory for Clean Energy[2021002] ; Fundamental Research Funds for the Central Universities[WK2060140026] ; Guangdong Natural Science Funds for Distinguished Young Scholar[2019B151502039] ; Fundamental Research Program of The Shenzhen Science and Technology Innovation Commission[JCYJ20190809164209485] ; National Synchrotron Radiation Laboratory[KY2060000173]

Chemistry

Chemistry, Multidisciplinary

WOS:000847498400001

ROYAL SOC CHEMISTRY

CHEMISTRY

Web of Science

1.Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Peoples R China
2.Univ Sci & Technol China, Hefei Natl Res Ctr Phys Sci Microscale, Dept Mat Sci & Engn, CAS Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
3.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China
4.Zhengzhou Univ, Key Lab Mat Proc & Mold, Minist Educ, Zhengzhou 450002, Peoples R China

Zheng, Kunxiong,Xu, Shitan,Yao, Yu,et al. Multi-component surface engineering of Na3V2(PO4)(2)O2F for low-temperature (-40 degrees C) sodium-ion batteries[J]. CHEMICAL COMMUNICATIONS,2022.

Zheng, Kunxiong.,Xu, Shitan.,Yao, Yu.,Chen, Dong.,Liu, Lin.,...&Yu, Yan.(2022).Multi-component surface engineering of Na3V2(PO4)(2)O2F for low-temperature (-40 degrees C) sodium-ion batteries.CHEMICAL COMMUNICATIONS.

Zheng, Kunxiong,et al."Multi-component surface engineering of Na3V2(PO4)(2)O2F for low-temperature (-40 degrees C) sodium-ion batteries".CHEMICAL COMMUNICATIONS (2022).