中文版 | English
Title

Superhydrophobic Shape-Stable Phase-Change Materials Based on Artificially Cultured Diatom Frustule-Derived Porous Ceramics

Author
Corresponding AuthorLyu, Sha; Sun, Dazhi
Publication Years
2022-08-01
DOI
Source Title
ISSN
2168-0485
Abstract
Solid-liquid phase-change materials (PCMs) offer exciting potential for energy conservation, but they suffer from a vital drawback of significant leakage. To overcome this issue, we develop a new strategy to obtain high-performance leakage-proof shape-stable phase-change materials (ss-PCMs) by the combina-tion of an inner porous frame and outer superhydrophobic covers. Paraffin wax as PCM was first trapped into artificially cultured diatom frustule-derived porous ceramics, which was then encapsulated using diatom frustule-based superhydrophobic coat-ings. The prepared ss-PCMs exhibit a wax loading of 52.28 wt % with a melting enthalpy of 117.5 Jmiddotg-1 and a high stability even after 500 thermal cycles as well as a 72.7% increase in thermal conductivity. In addition, the prepared ss-PCMs show a compressive strength of as high as 13.0 MPa. The superhydrophobic coatings provide ss-PCMs with superior chemical resistance and excellent mechanical robustness under long-distance abrasion, cyclic tape-peeling, and water jet impact. This porous ceramic-embedded, superhydrophobic coating-encapsulated strategy for obtaining high-performance ss-PCMs is expected to find potential applications in energy-efficient buildings, thermal management in electronic devices, self-cleaning materials, and so on.
Keywords
URL[Source Record]
Indexed By
SCI ; EI
Language
English
SUSTech Authorship
First ; Corresponding
Funding Project
Guangdong Provincial Key Laboratory Program[2021B1212040001]
WOS Research Area
Chemistry ; Science & Technology - Other Topics ; Engineering
WOS Subject
Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS Accession No
WOS:000847902600001
Publisher
EI Accession Number
20223612700124
EI Keywords
Coatings ; Compressive strength ; Energy efficiency ; Hydrophobicity ; Thermal conductivity
ESI Classification Code
Energy Conservation:525.2 ; Thermodynamics:641.1 ; Coating Materials:813.2 ; Physical Properties of Gases, Liquids and Solids:931.2
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:1
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/395944
DepartmentDepartment of Materials Science and Engineering
Affiliation
Southern Univ Sci & Technol, Dept Mat Sci & Engn, Guangdong Prov Key Lab Funct Oxide Mat & Devices, Shenzhen 518055, Guangdong, Peoples R China
First Author AffilicationDepartment of Materials Science and Engineering
Corresponding Author AffilicationDepartment of Materials Science and Engineering
First Author's First AffilicationDepartment of Materials Science and Engineering
Recommended Citation
GB/T 7714
Sun, Haoyang,Yang, Ye,Li, Tao,et al. Superhydrophobic Shape-Stable Phase-Change Materials Based on Artificially Cultured Diatom Frustule-Derived Porous Ceramics[J]. ACS Sustainable Chemistry & Engineering,2022.
APA
Sun, Haoyang.,Yang, Ye.,Li, Tao.,Lyu, Sha.,Chen, Fengfan.,...&Sun, Dazhi.(2022).Superhydrophobic Shape-Stable Phase-Change Materials Based on Artificially Cultured Diatom Frustule-Derived Porous Ceramics.ACS Sustainable Chemistry & Engineering.
MLA
Sun, Haoyang,et al."Superhydrophobic Shape-Stable Phase-Change Materials Based on Artificially Cultured Diatom Frustule-Derived Porous Ceramics".ACS Sustainable Chemistry & Engineering (2022).
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