Title | Intermolecular Metal-Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation |
Author | |
Corresponding Author | Shu, Wei |
Publication Years | 2022-09-01
|
DOI | |
Source Title | |
ISSN | 1433-7851
|
EISSN | 1521-3773
|
Abstract | Three-membered cyclic structures are widely existing in natural products and serve as enabling intermediates in organic synthesis. However, the efficient and straightforward access to such structures with diversity remains a formidable challenge. Herein, a general and practical protocol to aziridines and cyclopropanes synthesis using free XH2 (X=C or N) with alkenes by thianthrenation is presented. This metal-free protocol features the direct aziridination and cyclopropanation with unprotected XH2. Free sulfonamides, amides, carbamates, amines, and methylene with acidic protons, are good precursors, providing an attractive alternative for straightforward synthesis of aziridines and cyclopropanes from easily available starting materials. |
Keywords | |
URL | [Source Record] |
Indexed By | |
Language | English
|
Important Publications | NI Journal Papers
|
SUSTech Authorship | First
; Corresponding
|
Funding Project | NSFC
|
WOS Research Area | Chemistry
|
WOS Subject | Chemistry, Multidisciplinary
|
WOS Accession No | WOS:000849750000001
|
Publisher | |
EI Accession Number | 20223612697137
|
EI Keywords | Amides
; Amines
; Olefins
; Propane
; Sulfur compounds
|
ESI Classification Code | Metallurgy and Metallography:531
; Organic Compounds:804.1
|
ESI Research Field | CHEMISTRY
|
Data Source | Web of Science
|
Publication Status | 正式出版
|
Citation statistics |
Cited Times [WOS]:9
|
Document Type | Journal Article |
Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/395976 |
Department | Shenzhen Grubbs Institute 理学院_化学系 |
Affiliation | 1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China |
First Author Affilication | Shenzhen Grubbs Institute; Department of Chemistry |
Corresponding Author Affilication | Shenzhen Grubbs Institute; Department of Chemistry |
First Author's First Affilication | Shenzhen Grubbs Institute |
Recommended Citation GB/T 7714 |
Liu, Ming-Shang,Du, Hai-Wu,Cui, Jian-Fang,et al. Intermolecular Metal-Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022.
|
APA |
Liu, Ming-Shang,Du, Hai-Wu,Cui, Jian-Fang,&Shu, Wei.(2022).Intermolecular Metal-Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
|
MLA |
Liu, Ming-Shang,et al."Intermolecular Metal-Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022).
|
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
ACIE, 2022, 61, e202(4055KB) | Restricted Access | -- |
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