中文版 | English
Title

Intermolecular Metal-Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation

Author
Corresponding AuthorShu, Wei
Publication Years
2022-09-01
DOI
Source Title
ISSN
1433-7851
EISSN
1521-3773
Abstract

Three-membered cyclic structures are widely existing in natural products and serve as enabling intermediates in organic synthesis. However, the efficient and straightforward access to such structures with diversity remains a formidable challenge. Herein, a general and practical protocol to aziridines and cyclopropanes synthesis using free XH2 (X=C or N) with alkenes by thianthrenation is presented. This metal-free protocol features the direct aziridination and cyclopropanation with unprotected XH2. Free sulfonamides, amides, carbamates, amines, and methylene with acidic protons, are good precursors, providing an attractive alternative for straightforward synthesis of aziridines and cyclopropanes from easily available starting materials.

Keywords
URL[Source Record]
Indexed By
SCI ; EI
Language
English
Important Publications
NI Journal Papers
SUSTech Authorship
First ; Corresponding
Funding Project
NSFC
WOS Research Area
Chemistry
WOS Subject
Chemistry, Multidisciplinary
WOS Accession No
WOS:000849750000001
Publisher
EI Accession Number
20223612697137
EI Keywords
Amides ; Amines ; Olefins ; Propane ; Sulfur compounds
ESI Classification Code
Metallurgy and Metallography:531 ; Organic Compounds:804.1
ESI Research Field
CHEMISTRY
Data Source
Web of Science
Publication Status
正式出版
Citation statistics
Cited Times [WOS]:11
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/395976
DepartmentShenzhen Grubbs Institute
理学院_化学系
Affiliation
1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
First Author AffilicationShenzhen Grubbs Institute;  Department of Chemistry
Corresponding Author AffilicationShenzhen Grubbs Institute;  Department of Chemistry
First Author's First AffilicationShenzhen Grubbs Institute
Recommended Citation
GB/T 7714
Liu, Ming-Shang,Du, Hai-Wu,Cui, Jian-Fang,et al. Intermolecular Metal-Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022.
APA
Liu, Ming-Shang,Du, Hai-Wu,Cui, Jian-Fang,&Shu, Wei.(2022).Intermolecular Metal-Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA
Liu, Ming-Shang,et al."Intermolecular Metal-Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022).
Files in This Item:
File Name/Size DocType Version Access License
ACIE, 2022, 61, e202(4055KB) Restricted Access--
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