| Title | Free Aluminylenes: An Emerging Class of Compounds |
| Author | |
| Corresponding Author | Liu, Liu Leo |
| Publication Years | 2022-09-01
|
| DOI | |
| Source Title | |
| ISSN | 0947-6539
|
| EISSN | 1521-3765
|
| Abstract | Aluminylenes (R-Al) are aluminium analogs of carbenes. In contrast to isolable carbenes, aluminylenes are extremely rare species. In the past years, pioneered by Schnockel, Roesky and Power, a few free aluminylenes and their complexes have been reported. Such compounds have the aluminium atom in the oxidation state +I, which contrasts with classical organoaluminium derivatives that contain the element in the +III oxidation state. Aluminylenes, either in their free state or in the coordination sphere of a Lewis base, are capable of coordinating to transition metals and activating inert chemical bonds. Free aluminylenes are emerging as potent synthetic platforms for unusual aluminium species. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Natural Science Foundation of China[22101114]
; Guangdong Basic and Applied Basic Research Foundation[2022A1515011717]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
; China Postdoctoral Science Foundation (CPSF)["2021M691420","2022T150288"]
; CPSF[2022T150289]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000850668200001
|
| Publisher | |
| EI Accession Number | 20223712727115
|
| EI Keywords | Aluminum
; Bond strength (chemical)
; Ligands
; Organic compounds
; Transition metals
|
| ESI Classification Code | Metallurgy and Metallography:531
; Aluminum:541.1
; Physical Chemistry:801.4
; Chemical Reactions:802.2
; Chemical Products Generally:804
; Organic Compounds:804.1
|
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:8
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/401517 |
| Department | Department of Chemistry 深圳格拉布斯研究院 |
| Affiliation | 1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute; Southern University of Science and Technology |
| Corresponding Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute; Southern University of Science and Technology |
| First Author's First Affilication | Department of Chemistry; Shenzhen Grubbs Institute |
| Recommended Citation GB/T 7714 |
Zhang, Xin,Mei, Yanbo,Liu, Liu Leo. Free Aluminylenes: An Emerging Class of Compounds[J]. CHEMISTRY-A EUROPEAN JOURNAL,2022.
|
| APA |
Zhang, Xin,Mei, Yanbo,&Liu, Liu Leo.(2022).Free Aluminylenes: An Emerging Class of Compounds.CHEMISTRY-A EUROPEAN JOURNAL.
|
| MLA |
Zhang, Xin,et al."Free Aluminylenes: An Emerging Class of Compounds".CHEMISTRY-A EUROPEAN JOURNAL (2022).
|
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