Dehydro-Diels-Alder reaction and diamondization of bowl-shaped clusters C18Te3Br4(Bu-O)6

Jinbo Zhang1; Manli Ma; Rong Zhou; Hongqiang Chu; Xue Wang; Shaojie Wang; Huhu Tian4; Zhipeng Yan; Mingtao Li; Zhongyan Wu7; Bin Li7; Jiafeng Yan7; Lan Anh Thi Nguyen7; Rongxing Cao; Guoqing Wu; Xianghua Zeng; Hao-Li Zhang; Jaeyong Kim7; Lin Wang; Yongjun Tian

2022

Nano Research   Impact Factor & Quartile

1998-0124

Dehydro-Diels-Alder(DDA)reaction is a textbook reaction for preparing six-membered rings in solution but is scarcely seen in solid-state synthesis.In this work,using multiple characterization techniques,we demonstrate that the bowl-shaped clusters C18Te3Br4(Bu-O)6 might experience a DDA reaction at room temperature and high pressure between 5.5 and 7.4 GPa.Above 17.0 GPa,it is found that the bonding conversion from the intramolecular sp2 to the intermolecular spa occurred,in the form of pressure-induced diamondization.The recovered samples from 20.0 and 36.1 GPa showed incomplete reversibility,while the decompression-induced graphitization of glassy carbon was observed during decompression from 46.5 GPa.The electrochemical impedance spectroscopy results indicated that the transport properties changed from grain boundary dominant to grain dominant due to the DDA reaction and the grain boundary effect disappeared as the intermolecular sp3 bonding building-up and carrier transmission channel formation above 17.0 GPa.The results in this study open a new route to construct the crystalline carbon materials with different transport properties.

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1.College of Physical Science and Technology,Yangzhou University,Yangzhou 225002,China;Center for High Pressure Science(CHiPS),State Key Laboratory of Metastable Materials Science and Technology,Yanshan University,Qinhuangdao 066004,China
2.College of Physical Science and Technology,Yangzhou University,Yangzhou 225002,China
3.Center for High Pressure Science(CHiPS),State Key Laboratory of Metastable Materials Science and Technology,Yanshan University,Qinhuangdao 066004,China
4.State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,China;Baotou Research Institute of Rare Earths,Baotou 014000,China
5.Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology,Shenzhen 518055,China
6.Center for High Pressure Science and Technology Advanced Research,Shanghai 201203,China
7.Department of Physics,and High Pressure Research Center,Hanyang University,Seoul 04763,Republic of Korea
8.State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,China

Jinbo Zhang,Manli Ma,Rong Zhou,et al. Dehydro-Diels-Alder reaction and diamondization of bowl-shaped clusters C18Te3Br4(Bu-O)6[J]. Nano Research,2022,15(5):4606-4612.

Jinbo Zhang.,Manli Ma.,Rong Zhou.,Hongqiang Chu.,Xue Wang.,...&Yongjun Tian.(2022).Dehydro-Diels-Alder reaction and diamondization of bowl-shaped clusters C18Te3Br4(Bu-O)6.Nano Research,15(5),4606-4612.

Jinbo Zhang,et al."Dehydro-Diels-Alder reaction and diamondization of bowl-shaped clusters C18Te3Br4(Bu-O)6".Nano Research 15.5(2022):4606-4612.