Title | Impact of Polymer Rigidity on the Thermoresponsive Luminescence and Electron Spin Resonance of Polyester-Tethered Single Radicals |
Author | |
Corresponding Author | Wang,Mingfeng |
Publication Years | 2022
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DOI | |
Source Title | |
ISSN | 0024-9297
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EISSN | 1520-5835
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Volume | 55Issue:19 |
Abstract | Stable organic radicals represent a unique type of functional materials for a broad scope of applications in optoelectronic and spintronic devices. A central challenge toward these applications is how to suppress the inter-radical aggregation that often causes aggregation-induced photoluminescence quenching and limits the correlation lifetime of the electron spins from the radicals. Here, we report an effective approach to fine-tuning luminescence and spin dynamics using a series of polyester-tethered single radicals, with a common core of carbazole-triphenylmethyl radical but different chains of polyesters with distinct glass transition temperature and rigidity. The rigidity of the polymeric matrices plays a critical role in tuning the luminescence and electron spin resonance of the radicals. The tunable properties of luminescence and electron spin dynamics as well as the robust photostability of such polymer-tethered single radicals represent important attributes for cutting-edge applications in optoelectronic devices and quantum information technologies. |
URL | [Source Record] |
Indexed By | |
Language | English
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Important Publications | NI Journal Papers
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SUSTech Authorship | Others
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Funding Project | Chinese University of Hong Kong, Shenzhen[UDF01001806]
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WOS Research Area | Polymer Science
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WOS Subject | Polymer Science
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WOS Accession No | WOS:000867440500001
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Publisher | |
ESI Research Field | CHEMISTRY
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Scopus EID | 2-s2.0-85139407960
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Data Source | Scopus
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Citation statistics |
Cited Times [WOS]:0
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Document Type | Journal Article |
Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/406242 |
Department | Department of Electrical and Electronic Engineering |
Affiliation | 1.School of Science and Engineering,The Chinese University of Hong Kong,Shenzhen,518172,China 2.Department of Electrical and Electronic Engineering,Southern University of Science and Technology,Shenzhen,518055,China |
Recommended Citation GB/T 7714 |
Hou,Liman,Xu,Hongxue,Zhang,Xuanyu,et al. Impact of Polymer Rigidity on the Thermoresponsive Luminescence and Electron Spin Resonance of Polyester-Tethered Single Radicals[J]. MACROMOLECULES,2022,55(19).
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APA |
Hou,Liman.,Xu,Hongxue.,Zhang,Xuanyu.,Zhang,Yipeng.,Chen,Rui.,...&Wang,Mingfeng.(2022).Impact of Polymer Rigidity on the Thermoresponsive Luminescence and Electron Spin Resonance of Polyester-Tethered Single Radicals.MACROMOLECULES,55(19).
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MLA |
Hou,Liman,et al."Impact of Polymer Rigidity on the Thermoresponsive Luminescence and Electron Spin Resonance of Polyester-Tethered Single Radicals".MACROMOLECULES 55.19(2022).
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