| Title | Regulating Exposed Facets of Metal-Organic Frameworks for High-rate Alkaline Aqueous Zinc Batteries |
| Author | |
| Corresponding Author | Zhao, Lingzhi; Li, Hongfei; Zhi, Chunyi |
| Publication Years | 2022-10-01
|
| DOI | |
| Source Title | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| Abstract | Metal-organic frameworks (MOFs) have drawn growing attention as promising electrode candidates for rechargeable batteries. However, most studies focus on the direct use of MOF electrodes without any modification. Post-synthetic modification, a judicious tool to modify targeted properties of MOFs, has been long-neglected in the field of batteries. Herein, crystal-facet engineering is proposed to design MOF-based electrodes with high capacity and fast electrochemical kinetics. We found that a thermally-modified strategy can regulate the dominant exposed facet of Ni-based MOF (PFC-8). With the optimally exposed facets, the battery exhibited admirable rate capability (139.4 mAh g(-1) at 2.5 A g(-1) and 110.0 mAh g(-1) at 30 A g(-1)) and long-term stability. Furthermore, density functional theory calculations demonstrate that stronger OH- adsorption behaviors and optimized electronic structures induced by the regulated exposed facets boost the electrochemical performance. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
|
| SUSTech Authorship | Corresponding
|
| Funding Project | National Natural Science Foundation of China[22005207]
; Guangdong Basic and Applied Basic Research Foundation[
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000870762500001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:9
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/406873 |
| Department | School of System Design and Intelligent Manufacturing |
| Affiliation | 1.Songshan Lake Mat Lab, Dongguan 523808, Guangdong, Peoples R China 2.City Univ Hong Kong, Dept Mat Sci & Engn, 83 Tat Chee Ave, Hong Kong, Peoples R China 3.South China Normal Univ, Guangdong Prov Engn Technol Res Ctr Low Carbon &, Inst Semicond Sci & Technol, Guangzhou 510631, Peoples R China 4.Southern Univ Sci & Technol, Sch Syst Design & Intelligent Mfg, Shenzhen 518055, Guangdong, Peoples R China 5.City Univ Hong Kong, Hong Kong Inst Adv Study, Kowloon, Hong Kong 999077, Peoples R China 6.City Univ Hong Kong, Hong Kong Inst Clean Energy, Kowloon, Hong Kong 999077, Peoples R China |
| Corresponding Author Affilication | School of System Design and Intelligent Manufacturing |
| Recommended Citation GB/T 7714 |
Yang, Shuo,Lv, Haiming,Wang, Yanbo,et al. Regulating Exposed Facets of Metal-Organic Frameworks for High-rate Alkaline Aqueous Zinc Batteries[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022.
|
| APA |
Yang, Shuo.,Lv, Haiming.,Wang, Yanbo.,Guo, Xun.,Zhao, Lingzhi.,...&Zhi, Chunyi.(2022).Regulating Exposed Facets of Metal-Organic Frameworks for High-rate Alkaline Aqueous Zinc Batteries.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
|
| MLA |
Yang, Shuo,et al."Regulating Exposed Facets of Metal-Organic Frameworks for High-rate Alkaline Aqueous Zinc Batteries".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022).
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| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Regulating Exposed F（6479KB） | Restricted Access | -- | ||||
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