中文版 | English
Title

Acid Catalyzed Stereocontrolled Ferrier-Type Glycosylation Assisted by Perfluorinated Solvent

Author
Corresponding AuthorLu,Zhiqiang; Xiang,Shaohua; Fu,Yuqin
Publication Years
2022-11-01
DOI
Source Title
EISSN
1420-3049
Volume27Issue:21
Abstract
Described herein is the first application of perfluorinated solvent in the stereoselective formation of O-/S-glycosidic linkages that occurs via a Ferrier rearrangement of acetylated glycals. In this system, the weak interactions between perfluoro-n-hexane and substrates could augment the reactivity and stereocontrol. The initiation of transformation requires only an extremely low loading of resin-H and the mild conditions enable the accommodation of a broad spectrum of glycal donors and acceptors. The ‘green’ feature of this chemistry is demonstrated by low toxicity and easy recovery of the medium, as well as operational simplicity in product isolation.
Keywords
URL[Source Record]
Indexed By
Language
English
SUSTech Authorship
Corresponding
Funding Project
Henan Provincial Science and Technology Research Project[212102210549];Natural Science Foundation of Henan Province[212300410374];National Natural Science Foundation of China[21801112];Shenzhen Fundamental Research and Discipline Layout project[JCYJ20180305123508258];National Natural Science Foundation of China[U1304206];
WOS Research Area
Biochemistry & Molecular Biology ; Chemistry
WOS Subject
Biochemistry & Molecular Biology ; Chemistry, Multidisciplinary
WOS Accession No
WOS:000881582900001
Publisher
ESI Research Field
CHEMISTRY
Scopus EID
2-s2.0-85141593661
Data Source
Scopus
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/411818
DepartmentAcademy for Advanced Interdisciplinary Studies
Affiliation
1.College of Chemistry and Chemical Engineering and Henan Key Laboratory of Function-Oriented Porous Materials,Luoyang Normal University,Luoyang,471934,China
2.Hubei Key Laboratory of Natural Products Research and Development,Key Laboratory of Functional Yeast (China National Light Industry),College of Biological and Pharmaceutical Sciences,China Three Gorges University,Yichang,443002,China
3.Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology,Shenzhen,518055,China
Corresponding Author AffilicationAcademy for Advanced Interdisciplinary Studies
Recommended Citation
GB/T 7714
Lu,Zhiqiang,Li,Yanzhi,Xiang,Shaohua,et al. Acid Catalyzed Stereocontrolled Ferrier-Type Glycosylation Assisted by Perfluorinated Solvent[J]. Molecules,2022,27(21).
APA
Lu,Zhiqiang.,Li,Yanzhi.,Xiang,Shaohua.,Zuo,Mengke.,Sun,Yangxing.,...&Fu,Yuqin.(2022).Acid Catalyzed Stereocontrolled Ferrier-Type Glycosylation Assisted by Perfluorinated Solvent.Molecules,27(21).
MLA
Lu,Zhiqiang,et al."Acid Catalyzed Stereocontrolled Ferrier-Type Glycosylation Assisted by Perfluorinated Solvent".Molecules 27.21(2022).
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