Photocatalytic Oxidative Dehydrogenation of Propane for Selective Propene Production with TiO2
|Corresponding Author||Fan，Hongjun; Guo，Qing|
Oxidative dehydrogenation of propane (ODHP) as an exothermic process is a promising method to produce propene (C3H6) with lower energy consumption in chemical industry. However, the selectivity of the C3H6 product is always poor because of overoxidation. Herein, the ODHP reaction into C3H6 on a model rutile(R)-TiO2(110) surface at low temperature via photocatalysis has been realized successfully. The results illustrate that photocatalytic oxidative dehydrogenation of propane (C3H8) into C3H6 can occur efficiently on R-TiO2(110) at 90 K via a stepwise manner, in which the initial C-H cleavage occurs via the hole coupled C-H bond cleavage pathway followed by a radical mediated C-H cleavage to the C3H6 product. An exceptional selectivity of ∼90% for C3H6 production is achieved at about 13% propane conversion. The mechanistic model constructed in this study not only advances our understanding of C-H bond activation but also provides a new pathway for highly selective ODHP into C3H6 under mild conditions.
NI Journal Papers
First ; Corresponding
National Key R&D Program of China[2018YFE0203002] ; National Natural Science Foundation of China[
|WOS Research Area|
|WOS Accession No|
|EI Accession Number|
Chemical Bonds ; Chemical Industry ; Dehydrogenation ; Energy Utilization ; Oxide Minerals ; Photocatalysis ; Propane ; Propylene ; Temperature
|ESI Classification Code|
Minerals:482.2 ; Energy Utilization:525.3 ; Thermodynamics:641.1 ; Light/Optics:741.1 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Organic Compounds:804.1 ; Inorganic Compounds:804.2 ; Chemical Engineering, General:805
Cited Times [WOS]:1
|Document Type||Journal Article|
|Department||Department of Chemistry|
1.Shenzhen Key Laboratory of Energy Chemistry,Department of Chemistry,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
2.Shenzhen Institute of Advanced Technology,Chinese Academy of Sciences,Shenzhen,Guangdong,518055,China
3.State Key Laboratory of Molecular Reaction Dynamics,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,Liaoning,116023,China
4.Hefei National Laboratory,Hefei,230088,China
|First Author Affilication||Department of Chemistry|
|Corresponding Author Affilication||Department of Chemistry|
|First Author's First Affilication||Department of Chemistry|
Li，Fangliang,Wang，Binli,Chen，Xiao,et al. Photocatalytic Oxidative Dehydrogenation of Propane for Selective Propene Production with TiO2[J]. Journal of the American Chemical Society,2022.
Li，Fangliang.,Wang，Binli.,Chen，Xiao.,Lai，Yuemiao.,Wang，Tao.,...&Guo，Qing.(2022).Photocatalytic Oxidative Dehydrogenation of Propane for Selective Propene Production with TiO2.Journal of the American Chemical Society.
Li，Fangliang,et al."Photocatalytic Oxidative Dehydrogenation of Propane for Selective Propene Production with TiO2".Journal of the American Chemical Society (2022).
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