中文版 | English
Title

Developing Ru-Catalysts for Asymmetric Transfer Hydrogenation of Acyclic Imines

Author
Corresponding AuthorXu, Chen; Xing, Xiangyou
Publication Years
2022-11-18
DOI
Source Title
ISSN
1523-7060
EISSN
1523-7052
Volume24Issue:45Pages:8354-8358
Abstract

Asymmetric transfer hydrogenation (ATH) of acyclic imines has been rarely reported by using Ru-based catalysts. In this manuscript, employing Ru-catalysts with minimal stereo-genicity in combination with formic acid/triethylamine as the hydrogen donor enables a highly efficient ATH of N-diphenylphosphinyl acyclic imines. These substrates that include various aryl alkyl and heteroaryl alkyl substituted imines were all compatible with this catalytic system, and the corresponding reduced amines were obtained with excellent enantiomeric excess (ee's) and yields.

URL[Source Record]
Indexed By
Language
English
Important Publications
NI Journal Papers
SUSTech Authorship
Corresponding
Funding Project
Shenzhen Nobel Prize Scientists Laboratory Project[C17783101] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Natural Science Foundation of Guangdong Province[2021A1515010329] ; National Natural Science Foundation of China[K21211026] ; Shenzhen Science and Technology Program[
WOS Research Area
Chemistry
WOS Subject
Chemistry, Organic
WOS Accession No
WOS:000884878200001
Publisher
ESI Research Field
CHEMISTRY
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/412179
DepartmentShenzhen Grubbs Institute
理学院_化学系
Affiliation
1.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China
2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China
3.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China
First Author AffilicationShenzhen Grubbs Institute;  Department of Chemistry
Corresponding Author AffilicationShenzhen Grubbs Institute;  Department of Chemistry
Recommended Citation
GB/T 7714
He, Dongxu,Xu, Chen,Xing, Xiangyou. Developing Ru-Catalysts for Asymmetric Transfer Hydrogenation of Acyclic Imines[J]. ORGANIC LETTERS,2022,24(45):8354-8358.
APA
He, Dongxu,Xu, Chen,&Xing, Xiangyou.(2022).Developing Ru-Catalysts for Asymmetric Transfer Hydrogenation of Acyclic Imines.ORGANIC LETTERS,24(45),8354-8358.
MLA
He, Dongxu,et al."Developing Ru-Catalysts for Asymmetric Transfer Hydrogenation of Acyclic Imines".ORGANIC LETTERS 24.45(2022):8354-8358.
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