Acceptorless Dehydrogenation of Aliphatics, Amines, and Alcohols with Homogeneous Catalytic Systems

Zhou, Min-Jie1,2,3; Liu, Guixia1; Xu, Chen2,3; Huang, Zheng1,4

2022-11-01

10.1055/s-0042-1753053

SYNTHESIS-STUTTGART   Impact Factor & Quartile

0039-7881

1437-210X

The dehydrogenation of saturated substrates is fundamentally essential for producing value-added unsaturated organic molecules both in academia and industry. In recent years, homogeneously catalyzed acceptorless C-C, C-N, and C-O bond desaturations have attracted increasing attention due to high atom economy, environmentally benign nature, and wide availability of the starting materials. This short review discusses the acceptorless dehydrogenation of aliphatics, alcohols, and amines by homogeneous catalytic systems based on two categories of reaction mechanisms: thermal transition-metal-catalyzed two-electron pathway and photoredox catalyzed or electrochemically driven one-electron pathway.

acceptorless dehydrogenation homogeneous catalysis thermal transition-metal catalysis photoredox catalysis electrochemistry

SCI

English

Corresponding

National Basic Research Program of China["2021YFA1500100","2021YFA1501700"] ; National Natural Science Foundation of China["21825109","21821002","21732006","22072178","K21211026"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Shenzhen Science and Technology Program["KQTD20180411143514543","K20215006"] ; Youth Interdisciplinary Team[JCTD2021-11] ; Ningbo Municipal Bureau of Science and Technology[2019B10096]

Chemistry

Chemistry, Organic

WOS:000878373400004

GEORG THIEME VERLAG KG

CHEMISTRY

2-s2.0-85142173263

Web of Science

1.Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China
3.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China
4.Univ Chinese Acad Sci, Sch Chem & Mat Sci, Hangzhou Inst Adv Study, 1 Sublane Xiangshan, Hangzhou 310024, Peoples R China

Zhou, Min-Jie,Liu, Guixia,Xu, Chen,et al. Acceptorless Dehydrogenation of Aliphatics, Amines, and Alcohols with Homogeneous Catalytic Systems[J]. SYNTHESIS-STUTTGART,2022,55(4):547-564.

Zhou, Min-Jie,Liu, Guixia,Xu, Chen,&Huang, Zheng.(2022).Acceptorless Dehydrogenation of Aliphatics, Amines, and Alcohols with Homogeneous Catalytic Systems.SYNTHESIS-STUTTGART,55(4),547-564.

Zhou, Min-Jie,et al."Acceptorless Dehydrogenation of Aliphatics, Amines, and Alcohols with Homogeneous Catalytic Systems".SYNTHESIS-STUTTGART 55.4(2022):547-564.