Effects of fluorination on crystal structure and electrochemical performance of antiperovskite solid electrolytes
|Corresponding Author||Ruo,Zhao; Songbai,Han; Ruqiang,Zou; Yusheng,Zhao|
|Joint first author||Manrong,Song; Ruo,Zhao|
The development of all-solid-state lithium batteries (ASSLBs) depends on exploiting solid-state elec-trolytes (SSEs) with high ionic conductivity and electrochemical stability. Fluorination is generally con-sidered to be an effective strategy to improve the ionic conductivity and electrochemical stability of inorganic SSEs. Here, we report the partial fluorination of the chlorine sites in an antiperovskite, by which the orthorhombic Li2OHCl was transformed into cubic Li2OHCl0.9F0.1, resulting in a fourfold increase in ionic conductivity at 30 degrees C. The ab initio molecular dynamics simulations suggest that both the crystal symmetry and the anions electronegativity influence the diffusion of Li+ in the antiperovskite structure. Besides, from the perspective of experiments and calculations, it is confirmed that fluorination is a fea-sible method to improve the electrochemical stability of antiperovskite SSEs. The LiFePO4 | Li cell based on Li2OHCl0.9F0.1 is also assembled and exhibits stable cycle performance, which indicates that fluorina-tion of antiperovskite SSEs is an effective way to produce high-performance SSEs for practical application of ASSLBs.(c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.
National Key Research and Development Program of China[2020YFA0210701] ; National Natural Science Foundation of China[
|WOS Research Area|
Chemistry ; Energy & Fuels ; Engineering
Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
|WOS Accession No|
Web of Science
Cited Times [WOS]:3
|Document Type||Journal Article|
|Department||Academy for Advanced Interdisciplinary Studies|
1.School of Materials Science and Engineering, Peking University, Beijing 100871, China
2.Guangdong Provincial Key Laboratory of Energy Materials for Electric Power, Guangdong-Hong Kong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices, Academy for Advanced Interdisciplinary Studies，Southern University of Science and Technology, Shenzhen 518055, P. R. China
3.Institute for Advanced Study, Shenzhen University, Shenzhen 518055, Guangdong, China
|First Author Affilication||Academy for Advanced Interdisciplinary Studies|
|Corresponding Author Affilication||Academy for Advanced Interdisciplinary Studies|
Lei,Gao,Manrong,Song,Ruo,Zhao,et al. Effects of fluorination on crystal structure and electrochemical performance of antiperovskite solid electrolytes[J]. Journal of Energy Chemistry,2023,77.
Lei,Gao.,Manrong,Song.,Ruo,Zhao.,Songbai,Han.,Jinlong,Zhu.,...&Yusheng,Zhao.(2023).Effects of fluorination on crystal structure and electrochemical performance of antiperovskite solid electrolytes.Journal of Energy Chemistry,77.
Lei,Gao,et al."Effects of fluorination on crystal structure and electrochemical performance of antiperovskite solid electrolytes".Journal of Energy Chemistry 77(2023).
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