中文版 | English
Title

Transition-metal-catalyzed enantioselective C−H silylation

Author
Corresponding AuthorHe,Chuan
Publication Years
2022-11-17
DOI
Source Title
ISSN
2667-1107
EISSN
2667-1093
Volume2Issue:11Pages:2898-2928
Abstract
Organosilanes are important and valuable compounds that have found widespread applications in the fields of organic chemistry, agrochemistry, medicinal chemistry, and materials science. In modern synthetic chemistry, molecules featuring carbon−silicon bonds have attracted considerable interest given that these motifs can be efficiently converted to a wide range of functionalities. Among various approaches, transition-metal-catalyzed C−H silylation has emerged as a powerful tool for the synthesis of silicon-containing functional molecules, which has profoundly accelerated the iteration of organosilicon science. Despite the rapid development of C−H silylation, the enantioselective version of this elegant methodology was not known until 2013. In this review, we aim to summarize recent advances in the area of enantioselective C−H silylation mediated by chiral transition-metal catalysts, organized by the different forms of chirality of the enantioenriched organosilanes. We highlight the great potential of this methodology and intend to inspire further research and applications in this emerging area.
Keywords
URL[Source Record]
Language
English
SUSTech Authorship
First ; Corresponding
Funding Project
Guangdong Provincial Key Laboratory Of Catalysis[2020B121201002];National Natural Science Foundation of China[21901104];National Natural Science Foundation of China[22101113];National Natural Science Foundation of China[22101120];National Natural Science Foundation of China[22122102];
Scopus EID
2-s2.0-85141990313
Data Source
Scopus
Citation statistics
Cited Times [WOS]:5
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/416316
DepartmentDepartment of Chemistry
深圳格拉布斯研究院
Affiliation
1.Shenzhen Grubbs Institute and Department of Chemistry,Guangdong Provincial Key Laboratory of Catalysis,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
2.Sichuan Province Key Laboratory of Natural Products and Small Molecule Synthesis,School of New Energy Materials and Chemistry,Leshan Normal University,Leshan,Sichuan,614000,China
First Author AffilicationDepartment of Chemistry;  Shenzhen Grubbs Institute
Corresponding Author AffilicationDepartment of Chemistry;  Shenzhen Grubbs Institute
First Author's First AffilicationDepartment of Chemistry;  Shenzhen Grubbs Institute
Recommended Citation
GB/T 7714
Ge,Yicong,Huang,Xingfen,Ke,Jie,et al. Transition-metal-catalyzed enantioselective C−H silylation[J]. Chem Catalysis,2022,2(11):2898-2928.
APA
Ge,Yicong,Huang,Xingfen,Ke,Jie,&He,Chuan.(2022).Transition-metal-catalyzed enantioselective C−H silylation.Chem Catalysis,2(11),2898-2928.
MLA
Ge,Yicong,et al."Transition-metal-catalyzed enantioselective C−H silylation".Chem Catalysis 2.11(2022):2898-2928.
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