| Title | Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2-Insertion of CO into a U−N Bond |
| Author | |
| Corresponding Author | Maron，Laurent; Ye，Qing |
| Publication Years | 2022
|
| DOI | |
| Source Title | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| Abstract | In this contribution, we illustrate uranium complexes bearing a pendant borate (i.e. 1 and 2) or a pendant borane (i.e. 3 and 4) moiety via reaction of the highly strained uranacycle I with various 3-coordinate boranes. Complexes 3 and 4 represent the first examples of uranium complexes with a pendant borane Lewis acid. Moreover, complex 3 was capable of activation of CO, delivering a new CO activation mode, and an abnormal CO 1,2-insertion pathway into a U−N bond. The importance of the pendant borane moiety was confirmed by the controlled experiments. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
|
| SUSTech Authorship | Corresponding
|
| Funding Project | NSFC[22071095]
; Technology Innovation Commission of Shenzhen Municipality[20200925152822004]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000888860500001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Scopus EID | 2-s2.0-85143229175
|
| Data Source | Scopus
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/416550 |
| Department | Department of Chemistry |
| Affiliation | 1.School of Chemistry and Environmental Engineering,Anhui Polytechnic University,Wuhu,241000,China 2.Department of Chemistry,Southern University of Science and Technology,Shenzhen,1088 Xueyuan Blvd., Xili, Nanshan District,518055,China 3.Laboratoire de Physique et Chimie des Nanoobjets,INSA,CNRS,UPS,Université de Toulouse,Toulouse,31077,France 4.Institute for Inorganic Chemistry,Julius-Maximilians-Universität Würzburg,Würzburg,Am Hubland,97074,Germany 5.Institute for Sustainable Chemistry & Catalysis with Boron,Julius-Maximilians-Universität Würzburg,Würzburg,Am Hubland,97074,Germany |
| First Author Affilication | Department of Chemistry |
| Corresponding Author Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Su，Wei,Rajeshkumar，Thayalan,Xiang，Libo,et al. Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2-Insertion of CO into a U−N Bond[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022.
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| APA |
Su，Wei,Rajeshkumar，Thayalan,Xiang，Libo,Maron，Laurent,&Ye，Qing.(2022).Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2-Insertion of CO into a U−N Bond.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
|
| MLA |
Su，Wei,et al."Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2-Insertion of CO into a U−N Bond".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022).
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