| Title | Circularly Polarized Luminescence from Zero-Dimensional Hybrid Lead-Tin Bromide with Near-Unity Photoluminescence Quantum Yield |
| Author | |
| Corresponding Author | Quan，Zewei |
| Publication Years | 2022
|
| DOI | |
| Source Title | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| Abstract | Zero-dimensional (0D) hybrid metal halides with perfect host-guest structures are promising candidates to construct circularly polarized luminescence (CPL)-active materials. However, it still remains challenging to obtain 0D chiral metal halides with simultaneously strong CPL and high photoluminescence quantum yield. Here, a new enantiomeric pair of 0D hybrid lead-tin bromides, (RR/SS-CNH)PbSnBr ⋅ 2HO (R/S-PbSnBr ⋅ HO), is reported. The R/S-PbSnBr ⋅ HO compounds not only show intriguing self-trapped exciton emissions with near-unity quantum yield, but also present intense CPL with a dissymmetry factor g of ±3.0×10. Such CPL activities originate from the asymmetric [SnBr] luminophores in R/S-PbSnBr ⋅ HO, due to the induced structural chirality by the organic ligands via N−H⋅⋅⋅Br hydrogen bonds. Furthermore, CPL emissions with tunable colors from R/S-PbSnBr ⋅ HO and dehydrated compounds are reversibly observed, which extends their chiroptical applications. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | [52072166]
; [2016ZT06C279]
; [2022A1515010918]
; [RCJC2021060910444106]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000888393300001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Scopus EID | 2-s2.0-85143224227
|
| Data Source | Scopus
|
| Citation statistics |
Cited Times [WOS]:11
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/416552 |
| Department | Department of Chemistry 前沿与交叉科学研究院 |
| Affiliation | Department of Chemistry and Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology (SUSTech),Shenzhen,518055,China |
| First Author Affilication | Department of Chemistry; Academy for Advanced Interdisciplinary Studies |
| Corresponding Author Affilication | Department of Chemistry; Academy for Advanced Interdisciplinary Studies |
| First Author's First Affilication | Department of Chemistry; Academy for Advanced Interdisciplinary Studies |
| Recommended Citation GB/T 7714 |
Wei，Yi,Li，Chen,Li，Yawen,et al. Circularly Polarized Luminescence from Zero-Dimensional Hybrid Lead-Tin Bromide with Near-Unity Photoluminescence Quantum Yield[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022.
|
| APA |
Wei，Yi.,Li，Chen.,Li，Yawen.,Luo，Zhishan.,Wu，Xiaoyu.,...&Quan，Zewei.(2022).Circularly Polarized Luminescence from Zero-Dimensional Hybrid Lead-Tin Bromide with Near-Unity Photoluminescence Quantum Yield.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
|
| MLA |
Wei，Yi,et al."Circularly Polarized Luminescence from Zero-Dimensional Hybrid Lead-Tin Bromide with Near-Unity Photoluminescence Quantum Yield".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022).
|
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