| Title | The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers |
| Author | |
| Corresponding Author | Tan, Bin |
| Publication Years | 2022-11-01
|
| DOI | |
| Source Title | |
| ISSN | 0936-5214
|
| EISSN | 1437-2096
|
| Volume | 33Issue:20 |
| Abstract | The venerable axially chiral biaryl skeletons used widely in asymmetric catalysis such as BINOLs, NOBINs, QUINOLs, and CPAs possess a 2-naphthol moiety or are derived from the naphthol precursor. The hydroxy functionality offers the interaction point or serves as functional handle for synthetic elaboration. This prevalence and significance drive our studies to incorporate this nucleophile class to fabricate an assortment of atropisomers. By activating the reacting partners via distinctive mechanisms, the arylation of quinones, azo-or nitroso-naphthalenes, VQM intermediates, 1,2,4-triazole-3,5-diones, isoquinolines, and 1-bromo-2-naphthols with 2-naphthols were successfully attained. A concise account of these developments is provided in this article. 1 Introduction 2 Asymmetric Arylation with Quinones 3 Asymmetric Arylation with Electron-Deficient Arenes 4 Asymmetric Synthesis of Atropisomers with other Electrophiles 5 Conclusion |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Natural Science Foundation of China[2021YFF0701604]
; Guangdong Innovative Program["22271135","22231004"]
; Shenzhen Special Funds[2019BT02Y335]
; [JCYJ20210324120205016]
; [JCYJ20210324105005015]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Organic
|
| WOS Accession No | WOS:000890891700005
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/417049 |
| Department | Department of Chemistry 前沿与交叉科学研究院 深圳格拉布斯研究院 |
| Affiliation | 1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute; Academy for Advanced Interdisciplinary Studies |
| Corresponding Author Affilication | Department of Chemistry |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Xiang, Shao-Hua,Cheng, Jun Kee,Tan, Bin. The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers[J]. SYNLETT,2022,33(20).
|
| APA |
Xiang, Shao-Hua,Cheng, Jun Kee,&Tan, Bin.(2022).The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers.SYNLETT,33(20).
|
| MLA |
Xiang, Shao-Hua,et al."The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers".SYNLETT 33.20(2022).
|
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