中文版 | English
Title

Waste to Treasure: Regeneration of Porous Co-Based Catalysts from Spent LiCoO2 Cathode Materials for an Efficient Oxygen Evolution Reaction

Author
Corresponding AuthorLu, Xiao-Ying; Liu, Chen; Zhang, Zheming
Publication Years
2022-12-01
DOI
Source Title
ISSN
2168-0485
Abstract
The increasing demand for portable electronic devices and electric vehicles (EVs) has triggered the rapid growth of the rechargeable Li-ion battery (LIB) market. However, in the near future, it is predicted that a large amount of spent LIBs will be scrapped, imposing huge pressure on environmental protection and resource reclaiming. The effective recycling or regeneration of the spent LIBs not only relieves the environmental burdens but also avoids the waste of valuable metal resources. Herein, a porous Co9S8/Co3O4 heterostructure is successfully synthesized from the spent LiCoO2 (LCO) cathode materials via a conventional hydrometallurgy and sulfidation process. The fabricated Co9S8/Co3O4 catalyst exhibits high catalytic activity toward oxygen evolution reaction (OER) in an alkaline solution, with an overpotential of 274 mV to achieve the current density of 10 mA cm-2 and a Tafel slope of 48.7 mV dec-1. This work demonstrates a facile regeneration process of Co-based electrocatalysts from the spent LiCoO2 cathode materials for efficient oxygen evolution reaction.
Keywords
URL[Source Record]
Indexed By
Language
English
SUSTech Authorship
Others
Funding Project
Hong Kong Environment and Conservation Fund[21905180] ; National Natural Science Foundation of China[JCYJ20180305124237416] ; [39/2019]
WOS Research Area
Chemistry ; Science & Technology - Other Topics ; Engineering
WOS Subject
Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS Accession No
WOS:000894851600001
Publisher
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:1
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/417093
DepartmentDepartment of Materials Science and Engineering
Affiliation
1.Beijing Inst Technol, Shenzhen Automot Res Inst, Shenzhen 518118, Guangdong, Peoples R China
2.Beijing Inst Technol, Natl Engn Lab Elect Vehicles, Beijing 100081, Peoples R China
3.Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen Key Lab Polymer Sci & Technol, Shenzhen 518055, Peoples R China
4.Technol & Higher Educ Inst Hong Kong, Fac Sci & Technol, Hong Kong 999077, Peoples R China
5.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen Key Lab Interfacial Sci & Engn Mat, Shenzhen 518055, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Bian, Haidong,Wu, Wubin,Zhu, Yuanyi,et al. Waste to Treasure: Regeneration of Porous Co-Based Catalysts from Spent LiCoO2 Cathode Materials for an Efficient Oxygen Evolution Reaction[J]. ACS Sustainable Chemistry & Engineering,2022.
APA
Bian, Haidong.,Wu, Wubin.,Zhu, Yuanyi.,Tsang, Chi Him.,Cao, Yulin.,...&Zhang, Zheming.(2022).Waste to Treasure: Regeneration of Porous Co-Based Catalysts from Spent LiCoO2 Cathode Materials for an Efficient Oxygen Evolution Reaction.ACS Sustainable Chemistry & Engineering.
MLA
Bian, Haidong,et al."Waste to Treasure: Regeneration of Porous Co-Based Catalysts from Spent LiCoO2 Cathode Materials for an Efficient Oxygen Evolution Reaction".ACS Sustainable Chemistry & Engineering (2022).
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