| Title | Integration of Milstein Ru-PNN and Rh-Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes |
| Author | |
| Corresponding Author | Zhang, Runtong; Bai, Shao-Tao; Zhang, Xumu |
| Publication Years | 2022-12-01
|
| DOI | |
| Source Title | |
| ISSN | 0022-3263
|
| EISSN | 1520-6904
|
| Abstract | Converting cheap and abundant internal alkenes to value-added linear aldehydes is of great importance but not an addressed issue. In this paper, an integration of a Milstein-type Ru-PNN catalyst and our Rh- Tribi/Tetrabi catalyst was first demonstrated in highly improved isomerization linear selective hydroformylation of 2-, 3-, and 4-alkenes, yielding excellent linear selectivities and activities (linear selectivity improvements of 2.2-58%, up to 94.2-98.6%, and turnover numbers improvements of 61-335 TON, up to 385-851) compared to the Ru- PNN/Rh-Bisbi system. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | Guangdong Basic and Applied Basic Research Foundation[2021A1515110808]
; National Key R&D Program of China["2021YFA1500201","2021YFA0910800"]
; Chemistry and Chemical Engineering Guangdong Laboratory[2132013]
; National Natural Science Foundation of China[21991113]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Organic
|
| WOS Accession No | WOS:000893952000001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/417117 |
| Department | Department of Chemistry 前沿与交叉科学研究院 |
| Affiliation | 1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 3.Chem & Chem Engn Guangdong Lab, Shantou 515031, Peoples R China 4.Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong 999077, Peoples R China 5.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China 6.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Chemistry; Southern University of Science and Technology |
| Corresponding Author Affilication | Department of Chemistry; Southern University of Science and Technology; Academy for Advanced Interdisciplinary Studies; |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Zhang, Runtong,Yan, Xin,Chen, Caiyou,et al. Integration of Milstein Ru-PNN and Rh-Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes[J]. JOURNAL OF ORGANIC CHEMISTRY,2022.
|
| APA |
Zhang, Runtong.,Yan, Xin.,Chen, Caiyou.,Duan, Ya-Nan.,He, Xintong.,...&Zhang, Xumu.(2022).Integration of Milstein Ru-PNN and Rh-Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes.JOURNAL OF ORGANIC CHEMISTRY.
|
| MLA |
Zhang, Runtong,et al."Integration of Milstein Ru-PNN and Rh-Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes".JOURNAL OF ORGANIC CHEMISTRY (2022).
|
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