| Title | Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene-Phosphines |
| Author | |
| Corresponding Author | Yang, Limin; Tan, Bin; Wang, Jun (Joelle) |
| Publication Years | 2022-12-01
|
| DOI | |
| Source Title | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| Abstract | A Cu/CPA co-catalytic system has been developed for achieving the direct hydrophosphinylation of alkynes with phosphine oxides in delivering novel axially chiral phosphorus-containing alkenes in high yields and excellent enantioselectivities (up to 99 % yield and 99 % ee). DFT calculations were performed to elucidate the reaction pathway and the origin of enantiocontrol. This streamlined and modular methodology establishes a new platform for the design and application of new axially chiral styrene-phosphine ligands. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
; NI论文
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | [GRF 12301821]
; [21971102]
; [22231004]
; [21825105]
; [22271071]
; [2020B121201002]
; [2019BT02Y335]
; [KQTD20210811090112004]
; [LY20B020010]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000896830800001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:5
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/417122 |
| Department | Department of Chemistry 深圳格拉布斯研究院 |
| Affiliation | 1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 3.Hong Kong Baptist Univ, Dept Chem, Hong Kong, Peoples R China 4.Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 311121, Peoples R China |
| First Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute; Southern University of Science and Technology |
| Corresponding Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute; Southern University of Science and Technology |
| First Author's First Affilication | Department of Chemistry; Shenzhen Grubbs Institute |
| Recommended Citation GB/T 7714 |
Cai, Baohua,Cui, Yuan,Zhou, Jian,et al. Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene-Phosphines[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022.
|
| APA |
Cai, Baohua.,Cui, Yuan.,Zhou, Jian.,Wang, Yong-Bin.,Yang, Limin.,...&Wang, Jun .(2022).Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene-Phosphines.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
|
| MLA |
Cai, Baohua,et al."Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene-Phosphines".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022).
|
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Angew Chem Int Ed - （7414KB） | Restricted Access | -- | ||||
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