Visible-Light Mediated C-H Functionalizations: C-C Formation Enabled by Intermolecular Cleavage of Unactivated C-H Bonds
Wiley Online Library
CH bond is one of the most inert and massive chemical bonds in organic molecules. Thus, the direct conversion of various inert CH bonds to functionalized molecules via carbon–carbon or carbon–heteroatom bond formation represents one of the most ideal and straightforward means to build molecular complexity and is an important theme in organic chemistry, pharmaceutical chemistry, and material sciences. The direct functionalization of CH bond is step- and atom-economic, circumventing the prefunctionalization of molecules, thus attractive and highly desirable for organic synthesis. Due to the inertness of CH bonds and other associated issues, direct transformations from CH bonds remain challenging and attract great effort from the chemistry community. Among the strategies for the direct functionalizations of CH bonds, visible-light-mediated CH functionalizations have gained much attention from the community and have emerged as a promising tool for transforming CH bonds to other chemical bonds. This article summarizes the recent progress on the visible-light-mediated CH functionalization reactions enabled CC bond-forming processes, including representative examples of transforming ◂◽.▸Csp2H and ◂◽.▸Csp3H bonds into various carbon–carbon bonds.
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|Document Type||Book chapter|
|Department||Department of Chemistry|
Shenzhen Grubbs Inst, Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, Guangdong, Peoples R China
|First Author Affilication||Department of Chemistry; Shenzhen Grubbs Institute|
|Corresponding Author Affilication||Department of Chemistry; Shenzhen Grubbs Institute|
Shu W. Visible-Light Mediated C-H Functionalizations: C-C Formation Enabled by Intermolecular Cleavage of Unactivated C-H Bonds. Wiley Online Library:Wiley‐VCH GmbH,2022.
|Files in This Item:|
|Handbook of CH-Funct（3533KB）||Restricted Access||--|
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