中文版 | English
Title

Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)

Author
Corresponding AuthorWu, Yile; Liu, Liu Leo; Stephan, Douglas W.
Publication Years
2023-01-03
DOI
Source Title
ISSN
1359-7345
EISSN
1364-548X
Volume59Issue:3
Abstract
The aluminum analogue of Piers' borane, [HAl(C6F5)(2)](3)1, is prepared on a gram-scale. Density functional theory (DFT) calculations reveal 1 has a higher fluoride ion affinity (FIA) than Piers' borane, while the Al-H moiety proved to be a strong hydride donor, reacting with alcohol and terminal alkyne to give the corresponding dehydrogenative products 3 and 4. Hydroalumination product 5 was prepared via reaction of 1 with aldehyde. In addition, 1 catalyzes the hydrosilylation of alkynes and alkenes.
URL[Source Record]
Indexed By
Language
English
Important Publications
NI Journal Papers
SUSTech Authorship
Corresponding
Funding Project
Ningbo Natural Science Foundation[202003N4094] ; Ningbo University["421999362","422110973"] ; Ningbo Top Talent Project[215-432094250] ; National Natural Science Foundation of China["22271132","22101114"] ; Shenzhen Science and Technology Innovation Program[JCYJ20220530114806015] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
WOS Research Area
Chemistry
WOS Subject
Chemistry, Multidisciplinary
WOS Accession No
WOS:000895755400001
Publisher
ESI Research Field
CHEMISTRY
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/420810
DepartmentDepartment of Chemistry
深圳格拉布斯研究院
Affiliation
1.Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Zhejiang, Peoples R China
2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China
3.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China
4.Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada
Corresponding Author AffilicationDepartment of Chemistry;  Shenzhen Grubbs Institute;  Southern University of Science and Technology
Recommended Citation
GB/T 7714
Tan, Jingjie,Hu, Chaopeng,Yang, Xin,et al. Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)[J]. CHEMICAL COMMUNICATIONS,2023,59(3).
APA
Tan, Jingjie.,Hu, Chaopeng.,Yang, Xin.,Ju, Shaoying.,Cao, Levy L..,...&Stephan, Douglas W..(2023).Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3).CHEMICAL COMMUNICATIONS,59(3).
MLA
Tan, Jingjie,et al."Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)".CHEMICAL COMMUNICATIONS 59.3(2023).
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