| Title | Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3) |
| Author | |
| Corresponding Author | Wu, Yile; Liu, Liu Leo; Stephan, Douglas W. |
| Publication Years | 2023-01-03
|
| DOI | |
| Source Title | |
| ISSN | 1359-7345
|
| EISSN | 1364-548X
|
| Volume | 59Issue:3 |
| Abstract | The aluminum analogue of Piers' borane, [HAl(C6F5)(2)](3)1, is prepared on a gram-scale. Density functional theory (DFT) calculations reveal 1 has a higher fluoride ion affinity (FIA) than Piers' borane, while the Al-H moiety proved to be a strong hydride donor, reacting with alcohol and terminal alkyne to give the corresponding dehydrogenative products 3 and 4. Hydroalumination product 5 was prepared via reaction of 1 with aldehyde. In addition, 1 catalyzes the hydrosilylation of alkynes and alkenes. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
|
| SUSTech Authorship | Corresponding
|
| Funding Project | Ningbo Natural Science Foundation[202003N4094]
; Ningbo University["421999362","422110973"]
; Ningbo Top Talent Project[215-432094250]
; National Natural Science Foundation of China["22271132","22101114"]
; Shenzhen Science and Technology Innovation Program[JCYJ20220530114806015]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:000895755400001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/420810 |
| Department | Department of Chemistry 深圳格拉布斯研究院 |
| Affiliation | 1.Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Zhejiang, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 4.Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada |
| Corresponding Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute; Southern University of Science and Technology |
| Recommended Citation GB/T 7714 |
Tan, Jingjie,Hu, Chaopeng,Yang, Xin,et al. Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)[J]. CHEMICAL COMMUNICATIONS,2023,59(3).
|
| APA |
Tan, Jingjie.,Hu, Chaopeng.,Yang, Xin.,Ju, Shaoying.,Cao, Levy L..,...&Stephan, Douglas W..(2023).Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3).CHEMICAL COMMUNICATIONS,59(3).
|
| MLA |
Tan, Jingjie,et al."Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)(2)](3)".CHEMICAL COMMUNICATIONS 59.3(2023).
|
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