中文版 | English
Title

Three-Dimensional Silicene-Based Materials: A Universal Anode for Monovalent and Divalent Ion Batteries

Author
Corresponding AuthorWang, Yang-Gang
Publication Years
2023
DOI
Source Title
ISSN
1932-7447
EISSN
1932-7455
Abstract
In the pursuit of renewable energy storage technologies, ion batteries are intended to play a decisive role in accomplishing the energy requirements of the modern world. Herein, we theoretically designed porous three-dimensional (3D) allotropes of silicene (termed 3D-ortho-silicene and 3D-monosili-cene); these new 3D-silicenes exhibit stable structures, high porosities, conductive natures, and the high uptake of monovalent and multivalent ions. Owing to the unique 3D porous inner skeleton, small mass density, and inherent conductivity, both 3D-ortho-silicene and 3D-monosilicene materials indicate marvelous potential as anode materials. Importantly, 3D porous silicene structures exhibit high theoretical capacities in the range 718- 1117 mAh g-1 with high average potentials and extremely low volume expansion during the charge and discharge processes for lithium and calcium ions. This contribution not only expands the family of 3D-silicene allotropes but also predicts their electrochemical performances for ion batteries.
URL[Source Record]
Indexed By
Language
English
SUSTech Authorship
First ; Corresponding
Funding Project
NSFC of China[22022504] ; Guangdong "Pearl River" Talent Plan[2019QN01L353] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
WOS Research Area
Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS Subject
Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Accession No
WOS:000912738300001
Publisher
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/425209
DepartmentDepartment of Chemistry
Affiliation
1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalyt Chem, Shenzhen 518055, Guangdong, Peoples R China
3.Shenzhen Univ, Coll Phys & Optoelect Engn, Shenzhen 518060, Guangdong, Peoples R China
4.Univ Technol Sydney, Ctr Clean Energy Technol, Sch Math & Phys Sci, Sydney, NSW 2007, Australia
First Author AffilicationDepartment of Chemistry;  Southern University of Science and Technology
Corresponding Author AffilicationDepartment of Chemistry;  Southern University of Science and Technology
First Author's First AffilicationDepartment of Chemistry
Recommended Citation
GB/T 7714
Muhammad, Imran,Ahmed, Shehzad,Cao, Hao,et al. Three-Dimensional Silicene-Based Materials: A Universal Anode for Monovalent and Divalent Ion Batteries[J]. Journal of Physical Chemistry C,2023.
APA
Muhammad, Imran,Ahmed, Shehzad,Cao, Hao,Mahmood, Asif,&Wang, Yang-Gang.(2023).Three-Dimensional Silicene-Based Materials: A Universal Anode for Monovalent and Divalent Ion Batteries.Journal of Physical Chemistry C.
MLA
Muhammad, Imran,et al."Three-Dimensional Silicene-Based Materials: A Universal Anode for Monovalent and Divalent Ion Batteries".Journal of Physical Chemistry C (2023).
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