| Title | Eradicating beta-trap induced bleached-state degradation in amorphous TiO2 electrochromic films |
| Author | |
| Corresponding Author | Wen, Rui-Tao |
| Publication Years | 2023
|
| DOI | |
| Source Title | |
| ISSN | 2542-5293
|
| Volume | 30 |
| Abstract | Titanium dioxide (TiO2) draw great attention in developing electrochromic devices due to its low cost, dual-band optical modulation and wide potential window complementary to other EC films. Akin to other electrochromic oxides, TiO2 suffers from the tradeoff between cycling stability and large optical modulation because of the ion trapping effect. In this paper, we find formation of beta-traps can be prevented through adjusting the applied duration time at high potential, thus beta-traps induced bleached state degradation in amorphous TiO2 films can be eradicated. More importantly, we show the formed beta-traps locate at the TiO2/electrolyte interface, and are in-dependent of the employed electrolyte systems. The TiO2 based full electrochromic devices confirm beta-traps can be suppressed in a full device fashion. This work paves the way to understand the electrochromic performance degradation for oxide films upon square wave cycling and lays the foundation for adaptation in EC devices. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Natural Science Foundation of Guangdong[2022A1515010216]
; National Natural Science Foundation of China[52172294]
; "Shenzhen Science and Technology Innovation Commission[JCYJ20210324105402007]
; Guangdong Provincial Innovation and Entrepreneurship Project[2017ZT07C071]
; Guangdong Provincial Key Laboratory Program from the Department of Science and Technology of Guangdong Province[2021B1212040001]
; Shenzhen municipal government[Y01256130]
; Southern University of Science andTechnology[Y01256230]
|
| WOS Research Area | Materials Science
; Physics
|
| WOS Subject | Materials Science, Multidisciplinary
; Physics, Applied
|
| WOS Accession No | WOS:000918354100001
|
| Publisher | |
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:3
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/430726 |
| Department | Department of Materials Science and Engineering |
| Affiliation | 1.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Funct Oxide Mat & Devices, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Materials Science and Engineering |
| Corresponding Author Affilication | Department of Materials Science and Engineering; Southern University of Science and Technology |
| First Author's First Affilication | Department of Materials Science and Engineering |
| Recommended Citation GB/T 7714 |
Shao, Peipei,Huang, Siyuan,Li, Bowen,et al. Eradicating beta-trap induced bleached-state degradation in amorphous TiO2 electrochromic films[J]. Materials Today Physics,2023,30.
|
| APA |
Shao, Peipei,Huang, Siyuan,Li, Bowen,Huang, Qingjiao,Zhang, Yiwen,&Wen, Rui-Tao.(2023).Eradicating beta-trap induced bleached-state degradation in amorphous TiO2 electrochromic films.Materials Today Physics,30.
|
| MLA |
Shao, Peipei,et al."Eradicating beta-trap induced bleached-state degradation in amorphous TiO2 electrochromic films".Materials Today Physics 30(2023).
|
| Files in This Item: | There are no files associated with this item. | |||||
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