Title | High Zinc Utilization Aqueous Zinc Ion Batteries Enabled by 3D Printed Graphene Arrays |
Author | |
Corresponding Author | Lin, Meng |
Publication Years | 2023-01
|
DOI | |
Source Title | |
EISSN | 2405-8297
|
Volume | 54Pages:75-84 |
Abstract | The commercialization of aqueous zinc ion batteries requires good reversibility and high zinc utilization of zinc anode. For commonly applied 2D zinc anodes (zinc foils), their electrochemical performance and reversibility are often negatively correlated with the zinc utilization owing to the formation of zinc dendrites at the electrode-separator interphase. To overcome the disadvantages of 2D geometric design of zinc anode, this work fabricated two types of 3D printing graphene arrays (3DGs), tube arrays and pilar arrays, to simultaneously improve the reversibility and utilization of zinc anodes. The highly ordered 3D printed tubes/pillars array structures can accommodate the significant volume change during the zinc reversibly deposition/dissolution process and modify the zinc deposition on 3DGs. The array structures can also buffer the interaction between the metallic zinc and separator to protect AZIBs from short circuits. Consequently, the 3DGs showed considerable columbic efficiencies at current densities of 10–80 mA cm−2. The 3DGs@Zn anode delivered a lifespan of 1100 h in zinc symmetric cell at 2 mA cm−2 (1 mAh cm−2). The pouch cells fabricated with 3DGs@Zn anodes and V © 2022 Elsevier B.V. |
Indexed By | |
Language | English
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SUSTech Authorship | First
; Corresponding
|
Funding Project | This work was supported by Shenzhen Fundamental Research Programs (No. JCYJ20200109141216566 ), Guangdong Basic and Applied Basic Research Foundation (No. 2021A1515010412 ), Shenzhen Key Laboratory of Advanced Energy Storage ( 202204013000060 ), Shenzhen Science and Technology Innovation Commission ( GJHZ20200731095606021 , KQTD20190929172505711 , 20200925155544005 ) and the China Scholarship Council (CSC) for the financial support. The authors would also like to acknowledge the technical support from SUSTech Core Research Facilities.
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WOS Accession No | WOS:000879219500003
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Publisher | |
EI Accession Number | 20224313004907
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EI Keywords | 3D printers
; Deposition
; Electric batteries
; Graphene
; Ions
; Separators
; Vanadium pentoxide
; Zinc compounds
|
ESI Classification Code | Electric Batteries:702.1
; Electron Tubes:714.1
; Printing Equipment:745.1.1
; Nanotechnology:761
; Chemical Operations:802.3
; Chemical Products Generally:804
; Inorganic Compounds:804.2
|
Data Source | EV Compendex
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Citation statistics |
Cited Times [WOS]:17
|
Document Type | Journal Article |
Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/452691 |
Department | Department of Mechanical and Energy Engineering |
Affiliation | 1.Shenzhen Key Laboratory of Advanced Energy Storage, Southern University of Science and Technology, Shenzhen; 518055, China 2.Department of Mechanical and Energy Engineering, Southern University of Science and Technology, Shenzhen; 518055, China 3.SUSTech Energy Institute for Carbon Neutrality, Southern University of Science and Technology, Shenzhen; 518055, China |
First Author Affilication | Southern University of Science and Technology; Department of Mechanical and Energy Engineering; |
Corresponding Author Affilication | Department of Mechanical and Energy Engineering; Southern University of Science and Technology |
First Author's First Affilication | Southern University of Science and Technology |
Recommended Citation GB/T 7714 |
Wu, Buke,Guo, Binbin,Chen, Yuzhu,et al. High Zinc Utilization Aqueous Zinc Ion Batteries Enabled by 3D Printed Graphene Arrays[J]. Energy Storage Materials,2023,54:75-84.
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APA |
Wu, Buke.,Guo, Binbin.,Chen, Yuzhu.,Mu, Yongbiao.,Qu, Hongqiao.,...&Zeng, Lin.(2023).High Zinc Utilization Aqueous Zinc Ion Batteries Enabled by 3D Printed Graphene Arrays.Energy Storage Materials,54,75-84.
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MLA |
Wu, Buke,et al."High Zinc Utilization Aqueous Zinc Ion Batteries Enabled by 3D Printed Graphene Arrays".Energy Storage Materials 54(2023):75-84.
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