| Title | Thermo- and photo-induced electron transfer in a series of [Fe2Co2] capsules |
| Author | |
| Corresponding Author | Holmes, Stephen M. M.; Zhang, Yuan-Zhu |
| Publication Years | 2023-02-07
|
| DOI | |
| Source Title | |
| ISSN | 1477-9226
|
| EISSN | 1477-9234
|
| Volume | 52Issue:6 |
| Abstract | Recently, a family of [Fe2Co2] molecular capsules that display tunable electron transfer-coupled spin transition (ETCST) behavior were reported via a smart approach through Schiff-base condensation of aldehyde-functionalized 2,2-bipyridines (bpy(CHO)) and 1,7-heptanediamine (H2N(CH2)(7)NH2). Here, three more capsule complexes {[(Tp(R))Fe(CN)(3)](2)[Co(bpy(C=N(CH2)nN=C)bpy)](2)[ClO4](2)center dot n(solvent) (1, Tp(R) = Tp*, n = 5, sol = 8DMF; 2, Tp(R) = Tp(Me), n = 9, sol = 5MeCN; and 3, Tp(R) = Tp*, n = 11, sol = 5MeCN), where Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate and Tp(Me) = hydridotris(3-methylpyrazol-1-yl)borate are reported, demonstrating a successful extension of such an approach with other alkyldiamines of different lengths. Combined X-ray crystallographic, infrared spectroscopic and magnetic studies reveal incomplete electron transfer with either changing temperature or upon light exposure. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Science Foundation["CHE-1214063","CHE-1800578"]
; Stable Support Plan Program of Shenzhen Natural Science Fund[20200925151834005]
; Guangdong Basic and Applied Basic Research Foundation[2022A1515011818]
; National Natural Science Foundation of China["21901108","22173043"]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Inorganic & Nuclear
|
| WOS Accession No | WOS:000919090600001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/475043 |
| Department | Department of Chemistry |
| Affiliation | 1.Southern Univ Sci & Technol SUSTech, Dept Chem, Shenzhen 518055, Peoples R China 2.Univ Missouri, Dept Chem & Biochem, St Louis, MO 63121 USA 3.Univ Missouri, Ctr Nanosci, St Louis, MO 63121 USA |
| First Author Affilication | Department of Chemistry |
| Corresponding Author Affilication | Department of Chemistry |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Meng, Lingyi,Deng, Yi-Fei,Holmes, Stephen M. M.,et al. Thermo- and photo-induced electron transfer in a series of [Fe2Co2] capsules[J]. DALTON TRANSACTIONS,2023,52(6).
|
| APA |
Meng, Lingyi,Deng, Yi-Fei,Holmes, Stephen M. M.,&Zhang, Yuan-Zhu.(2023).Thermo- and photo-induced electron transfer in a series of [Fe2Co2] capsules.DALTON TRANSACTIONS,52(6).
|
| MLA |
Meng, Lingyi,et al."Thermo- and photo-induced electron transfer in a series of [Fe2Co2] capsules".DALTON TRANSACTIONS 52.6(2023).
|
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