中文版 | English
Title

Thermo- and photo-induced electron transfer in a series of [Fe2Co2] capsules

Author
Corresponding AuthorHolmes, Stephen M. M.; Zhang, Yuan-Zhu
Publication Years
2023-02-07
DOI
Source Title
ISSN
1477-9226
EISSN
1477-9234
Volume52Issue:6
Abstract
Recently, a family of [Fe2Co2] molecular capsules that display tunable electron transfer-coupled spin transition (ETCST) behavior were reported via a smart approach through Schiff-base condensation of aldehyde-functionalized 2,2-bipyridines (bpy(CHO)) and 1,7-heptanediamine (H2N(CH2)(7)NH2). Here, three more capsule complexes {[(Tp(R))Fe(CN)(3)](2)[Co(bpy(C=N(CH2)nN=C)bpy)](2)[ClO4](2)center dot n(solvent) (1, Tp(R) = Tp*, n = 5, sol = 8DMF; 2, Tp(R) = Tp(Me), n = 9, sol = 5MeCN; and 3, Tp(R) = Tp*, n = 11, sol = 5MeCN), where Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate and Tp(Me) = hydridotris(3-methylpyrazol-1-yl)borate are reported, demonstrating a successful extension of such an approach with other alkyldiamines of different lengths. Combined X-ray crystallographic, infrared spectroscopic and magnetic studies reveal incomplete electron transfer with either changing temperature or upon light exposure.
URL[Source Record]
Indexed By
Language
English
SUSTech Authorship
First ; Corresponding
Funding Project
National Science Foundation["CHE-1214063","CHE-1800578"] ; Stable Support Plan Program of Shenzhen Natural Science Fund[20200925151834005] ; Guangdong Basic and Applied Basic Research Foundation[2022A1515011818] ; National Natural Science Foundation of China["21901108","22173043"]
WOS Research Area
Chemistry
WOS Subject
Chemistry, Inorganic & Nuclear
WOS Accession No
WOS:000919090600001
Publisher
ESI Research Field
CHEMISTRY
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/475043
DepartmentDepartment of Chemistry
Affiliation
1.Southern Univ Sci & Technol SUSTech, Dept Chem, Shenzhen 518055, Peoples R China
2.Univ Missouri, Dept Chem & Biochem, St Louis, MO 63121 USA
3.Univ Missouri, Ctr Nanosci, St Louis, MO 63121 USA
First Author AffilicationDepartment of Chemistry
Corresponding Author AffilicationDepartment of Chemistry
First Author's First AffilicationDepartment of Chemistry
Recommended Citation
GB/T 7714
Meng, Lingyi,Deng, Yi-Fei,Holmes, Stephen M. M.,et al. Thermo- and photo-induced electron transfer in a series of [Fe2Co2] capsules[J]. DALTON TRANSACTIONS,2023,52(6).
APA
Meng, Lingyi,Deng, Yi-Fei,Holmes, Stephen M. M.,&Zhang, Yuan-Zhu.(2023).Thermo- and photo-induced electron transfer in a series of [Fe2Co2] capsules.DALTON TRANSACTIONS,52(6).
MLA
Meng, Lingyi,et al."Thermo- and photo-induced electron transfer in a series of [Fe2Co2] capsules".DALTON TRANSACTIONS 52.6(2023).
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