| Title | Organocatalytic Regio- and Enantioselective Allylic Alkylation of Indolin-2-imines with MBH Carbonates toward 3-Allylindoles |
| Author | |
| Corresponding Author | Li, Pengfei |
| Publication Years | 2023
|
| DOI | |
| Source Title | |
| ISSN | 0022-3263
|
| EISSN | 1520-6904
|
| Abstract | An organocatalytic asymmetric C3-allylic alkylation of indolone-2-imines with MBH carbonates has been developed for the first time. As opposed to previous reports, an "interrupted" annulation was achieved, affording 3-allylindoles in generally high yields with excellent stereoselectivities. The representative scale-up reaction and transformation of 3-allylindoles were examined. A possible mechanism was also proposed. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | Corresponding
|
| Funding Project | National Natural Science Foundation of China[21871128]
; Guangdong Innovative Program[2019BT02Y335]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Organic
|
| WOS Accession No | WOS:000925702800001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:1
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/479593 |
| Department | Shenzhen Grubbs Institute 理学院_化学系 |
| Affiliation | 1.Harbin Inst Technol, Sch Resources & Environm, Harbin 150080, Peoples R China 2.Southern Univ Sci & Technol SUSTech, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol SUSTech, Coll Sci, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China |
| Corresponding Author Affilication | Shenzhen Grubbs Institute; Department of Chemistry |
| Recommended Citation GB/T 7714 |
Chen, Lunfeng,Li, Pengfei. Organocatalytic Regio- and Enantioselective Allylic Alkylation of Indolin-2-imines with MBH Carbonates toward 3-Allylindoles[J]. JOURNAL OF ORGANIC CHEMISTRY,2023.
|
| APA |
Chen, Lunfeng,&Li, Pengfei.(2023).Organocatalytic Regio- and Enantioselective Allylic Alkylation of Indolin-2-imines with MBH Carbonates toward 3-Allylindoles.JOURNAL OF ORGANIC CHEMISTRY.
|
| MLA |
Chen, Lunfeng,et al."Organocatalytic Regio- and Enantioselective Allylic Alkylation of Indolin-2-imines with MBH Carbonates toward 3-Allylindoles".JOURNAL OF ORGANIC CHEMISTRY (2023).
|
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