中文版 | English
Title

Visible-Light-Mediated Deacylated Alkynylation of Unstrained Ketone

Author
Corresponding AuthorChen,Shuguang
Publication Years
2023-02-24
DOI
Source Title
ISSN
1523-7060
EISSN
1523-7052
Volume25Issue:7Pages:1166-1171
Abstract
Deconstructive alkynylation of an unstrained ketone catalyzed by an organic photocatalyst under blue light irradiation is reported for the first time. A broad substrate scope with up to 63 examples, excellent functional group tolerance, and gram scale reaction demonstrated the practicality of this novel alkynylation method. The dihydroquinazolinone derivative of trifluoroacetophenone had been proved to have potential as a novel trifluoromethylation reagent after working well for the trifluoromethylation reaction with various alkynyl bromides.
URL[Source Record]
Indexed By
Language
English
Important Publications
NI Journal Papers
SUSTech Authorship
Others
Funding Project
National Natural Science Foundation of China[21772001] ; University Synergy Innovation Program of Anhui Province[GXXT-2020-074] ; Natural Science Foundation of AnHui Province, China[2108085QB77] ; Anhui Provincial Nature Science Foundation[2108085MB64]
WOS Research Area
Chemistry
WOS Subject
Chemistry, Organic
WOS Accession No
WOS:000937480500001
Publisher
ESI Research Field
CHEMISTRY
Scopus EID
2-s2.0-85148365467
Data Source
Scopus
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/497248
DepartmentDepartment of Chemistry
深圳格拉布斯研究院
Affiliation
1.Key Laboratory of Functional Molecular Solids,Ministry of Education,Anhui Laboratory of Molecule-Based Materials (State Key Laboratory Cultivation Base),College of Chemistry and Materials Science,Anhui Normal University,Wuhu,241000,China
2.Institute of Advanced Technology,University of Science and Technology of China,Hefei,230026,China
3.Shenzhen Grubbs Institute and Department of Chemistry,Guang-dong Provincial Key Laboratory of Catalysis,Southern University of Science and Technology,Shenzhen,518055,China
Recommended Citation
GB/T 7714
Wu,Hao,Chen,Shuguang,Xiao,Dengmengfei,et al. Visible-Light-Mediated Deacylated Alkynylation of Unstrained Ketone[J]. ORGANIC LETTERS,2023,25(7):1166-1171.
APA
Wu,Hao.,Chen,Shuguang.,Xiao,Dengmengfei.,Li,Feng.,Zhou,Kaiyuan.,...&Shang,Yongjia.(2023).Visible-Light-Mediated Deacylated Alkynylation of Unstrained Ketone.ORGANIC LETTERS,25(7),1166-1171.
MLA
Wu,Hao,et al."Visible-Light-Mediated Deacylated Alkynylation of Unstrained Ketone".ORGANIC LETTERS 25.7(2023):1166-1171.
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