| Title | Utilization of a Tris(carbene)borate Ligand for Umpolung Reactivity of a Nucleophilic Tin(II) Cation Salt |
| Author | |
| Corresponding Author | Liu, Liu Leo |
| Publication Years | 2023-02-27
|
| DOI | |
| Source Title | |
| ISSN | 0020-1669
|
| EISSN | 1520-510X
|
| Volume | 62Issue:8 |
| Abstract | We show that a tris(carbene)borate (TCB) ligand, namely [PhB(tBuIm)3]- ([PhB(tBuIm)3]- = phenyltris(3-tert-butylimidazol-2-ylidene)-borato), is capable of stabilizing an unprecedented nucleophilic Sn(II) cation salt. Unlike known Sn(II) cations, the strong electron-donating ability of [PhB-(tBuIm)3]- makes the cationic tin atom electron-rich, sigma-donating yet slightly pi- accepting, which allows for the ensuing facile oxidation with o-chloranil and S8 as well as coordination with coinage metals. The former oxidations give the Sn(IV) cation salts, while the latter reactions produce the metal complexes. The electronic structures of these species are thoroughly probed by quantum chemical computations. These results uncover an added role for TCB ligands in isolating unprecedented p-block species. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
; NI论文
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Natural Science Foundation of China["22271132","22101114"]
; Shenzhen Science and Technology Innovation Program[JCYJ20220530114806015]
; Guangdong Basic and Applied Basic Research Foundation[2022A1515011717]
; Guang-dong Provincial Key Laboratory of Catalysis[2020B121201002]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Inorganic & Nuclear
|
| WOS Accession No | WOS:000938754300001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:1
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/501544 |
| Department | Department of Chemistry |
| Affiliation | 1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Chemistry; Southern University of Science and Technology |
| Corresponding Author Affilication | Department of Chemistry; Southern University of Science and Technology |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Hu, Chaopeng,Liu, Liu Leo. Utilization of a Tris(carbene)borate Ligand for Umpolung Reactivity of a Nucleophilic Tin(II) Cation Salt[J]. INORGANIC CHEMISTRY,2023,62(8).
|
| APA |
Hu, Chaopeng,&Liu, Liu Leo.(2023).Utilization of a Tris(carbene)borate Ligand for Umpolung Reactivity of a Nucleophilic Tin(II) Cation Salt.INORGANIC CHEMISTRY,62(8).
|
| MLA |
Hu, Chaopeng,et al."Utilization of a Tris(carbene)borate Ligand for Umpolung Reactivity of a Nucleophilic Tin(II) Cation Salt".INORGANIC CHEMISTRY 62.8(2023).
|
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