中文版 | English
Title

Phthalocyanine in perovskite solar cells: a review

Author
Corresponding AuthorLiu, Xiaoyuan; Xu, Zong-Xiang
Publication Years
2023-02-01
DOI
Source Title
EISSN
2052-1537
Volume7Pages:1704-1736
Abstract

Presently, due to the rapid development of perovskite solar cells (PSCs), their commercialization is not only attractive but perhaps the only choice to replace both thin film photovoltaics (PV) and conventional silicon PV. However, although the power conversion efficiency (PCE) of PSCs is has reached above 25%, which is suitable for their commercialization, their poor long-term stability with scalability remains a challenge due to the sensitivity of perovskites under ambient conditions. Therefore, the top and bottom layers sandwiching the perovskite layer are critical. In this case, the charge transport layers (CTLs) not only enable charge extraction but also play the role of encrusting, passivating, and supporting the perovskite layer. Therefore, the perovskite interface has a dominant influence on the performances of PSCs. In this case, phthalocyanines (Pcs) have a large pi-conjugated framework, outstanding thermal stability, excellent physical/chemical stability, low cost, and can be endowed with a tunable energy band, good carrier mobility, solubility in common solvents, and facile synthesis through their appropriate design, making them a robust charge selective layer, passivation layer or both in PSCs. In this review, we summarize the studies on the application of Pc compounds in PSCs, including dopant-free macrocycle molecules, from the perspectives of molecular engineering, doped hole transporting material (HTM), and employment of Pcs as additives in the perovskite layer or HTMs. This review provides helpful insight for further enhancing the efficiency of PSC devices, while improving their long-term operational life by utilizing Pc materials.

URL[Source Record]
Indexed By
Language
English
SUSTech Authorship
First ; Corresponding
Funding Project
National Science Foundation of China[21975116] ; General Program of Basic Research in Shenzhen[JCYJ20220530112801004]
WOS Research Area
Chemistry ; Materials Science
WOS Subject
Chemistry, Multidisciplinary ; Materials Science, Multidisciplinary
WOS Accession No
WOS:000943844500001
Publisher
Data Source
Web of Science
Publication Status
正式出版
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/513445
DepartmentDepartment of Chemistry
Affiliation
1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
2.Univ Surrey, Adv Technol Inst, Dept Elect & Elect Engn, Guildford GU2 7XH, Surrey, England
First Author AffilicationDepartment of Chemistry
Corresponding Author AffilicationDepartment of Chemistry
First Author's First AffilicationDepartment of Chemistry
Recommended Citation
GB/T 7714
Rezaee, Ehsan,Khan, Danish,Cai, Siyuan,et al. Phthalocyanine in perovskite solar cells: a review[J]. MATERIALS CHEMISTRY FRONTIERS,2023,7:1704-1736.
APA
Rezaee, Ehsan.,Khan, Danish.,Cai, Siyuan.,Dong, Lei.,Xiao, Hui.,...&Xu, Zong-Xiang.(2023).Phthalocyanine in perovskite solar cells: a review.MATERIALS CHEMISTRY FRONTIERS,7,1704-1736.
MLA
Rezaee, Ehsan,et al."Phthalocyanine in perovskite solar cells: a review".MATERIALS CHEMISTRY FRONTIERS 7(2023):1704-1736.
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Mater. Chem. Front.,(8946KB) Restricted Access--
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