中文版 | English
Title

{P4Mo6}-Based Complex Modified by Graphite Applied in Electrochemical Ultra-trace Detection of Nitro-antibiotics under Strongly Acidic Conditions

Author
Corresponding AuthorXu, Na; Wang, Xiu-Li
Publication Years
2023-02-01
DOI
Source Title
ISSN
1528-7483
EISSN
1528-7505
Volume23Issue:2Pages:694-703
Abstract
The electrochemical analytical technology at the molecular level is of great importance for the successive and simultaneous determination of ultra-trace antibiotics. Herein, a complex constructed by the {P4Mo6} unit has been synthesized under the hydrothermal condition with the formula [H2(3-AP)]6{Co[Mo6O12(OH)3(HPO4)2(PO4)2]2} (3-AP = 3-ammethylpyridine) (1). Complex 1 was modified by different ratios of graphite powder (GP) to produce the 1/GP composites via a physical method. The results showed that the optimal ratio of 1 to GP is 1:2.6, which was denoted as the 1/GP-2.6 composite. The 1/GP-2.6 composite as a superior electrochemical sensor has achieved the ultra-trace electrochemical detection of metronidazole (MDZ), dimetronidazole (DTZ), nitrofurantoin (NFT), and nitrofurazone (NFZ) under the best condition. Moreover, the 1/GP-2.6 composite demonstrated high sensitivity and anti-interference ability. In addition, the possible electrochemical detection mechanism of four nitro-antibiotics has been analyzed.
© 2022 American Chemical Society.
URL[Source Record]
Indexed By
EI ; SCI
Language
English
SUSTech Authorship
Corresponding
Funding Project
This work was financially supported by the National Natural Science Foundation of China (nos. 21971024 and 22101030), the Liaoning Revitalization Talents Program (XLYC190211), and the Doctoral Scientific Research Foundation of Liaoning Province (no. 2021-BS-255).
WOS Research Area
Chemistry ; Crystallography ; Materials Science
WOS Subject
Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
WOS Accession No
WOS:000901994800001
Publisher
EI Accession Number
20225213294824
EI Keywords
Chemical detection ; Electrochemical sensors ; Graphite ; Trace analysis
ESI Classification Code
Medicine and Pharmacology:461.6 ; Control Instrumentation:732.2 ; Chemistry:801 ; Electrochemistry:801.4.1
ESI Research Field
CHEMISTRY
Data Source
EV Compendex
Citation statistics
Cited Times [WOS]:2
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/519717
DepartmentDepartment of Chemistry
Affiliation
1.College of Chemistry and Materials Engineering, Liaoning Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou; 121013, China
2.Department of Chemistry, Southern University of Science and Technology, Shenzhen; 518055, China
Corresponding Author AffilicationDepartment of Chemistry
Recommended Citation
GB/T 7714
Wang, Jinling,Xu, Na,Chang, Zhihan,et al. {P4Mo6}-Based Complex Modified by Graphite Applied in Electrochemical Ultra-trace Detection of Nitro-antibiotics under Strongly Acidic Conditions[J]. CRYSTAL GROWTH & DESIGN,2023,23(2):694-703.
APA
Wang, Jinling,Xu, Na,Chang, Zhihan,&Wang, Xiu-Li.(2023).{P4Mo6}-Based Complex Modified by Graphite Applied in Electrochemical Ultra-trace Detection of Nitro-antibiotics under Strongly Acidic Conditions.CRYSTAL GROWTH & DESIGN,23(2),694-703.
MLA
Wang, Jinling,et al."{P4Mo6}-Based Complex Modified by Graphite Applied in Electrochemical Ultra-trace Detection of Nitro-antibiotics under Strongly Acidic Conditions".CRYSTAL GROWTH & DESIGN 23.2(2023):694-703.
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