中文版 | English
Title

Adsorption mechanism of styryl phosphonate ester as collector in ilmenite flotation

Author
Corresponding AuthorLIU, Cheng; YANG, Si-yuan
Publication Years
2022-12
DOI
Source Title
ISSN
1003-6326
EISSN
2210-3384
Volume32Pages:4088-4098
Abstract
A styryl phosphonate ester (SPE) collector was used to improve the flotation performance of ilmenite, and the adsorption mechanism and model were revealed and established, respectively. Microflotation tests showed that SPE exhibited a stronger collecting ability for ilmenite than the traditional collector styrene phosphonic acid (SPA). Zeta potential measurements revealed that both SPE and SPA could negatively shift the zeta potential of ilmenite, while SPE had more effects than SPA, suggesting the stronger adsorption of SPE. The analysis of X-ray photoelectron spectroscopy confirmed the chemisorption of SPA and SPE onto the Fe/Ti sites of ilmenite. According to frontier orbital theory, the chemical activities of SPE are greater than those of SPA. The partial densities of states analysis indicated that the PO—H groups of the collectors could interact with the Ti/Fe atoms of the ilmenite surface to generate a stable four-membered ring. The bonding model of the collector and (104) ilmenite surface showed that the adsorption energy of SPE was higher than that of SPA. Overall, SPE presented a better collecting ability and interaction effect for ilmenite flotation than SPA, and had the potential to replace SPA in the industry.
© 2022 The Nonferrous Metals Society of China
Indexed By
Language
English
SUSTech Authorship
Others
Funding Project
The authors acknowledge the support from the National Natural Science Foundation of China (Nos. 51904214 and 51804238), the Young Elite Scientists Sponsorship Program by CAST (No. YESS20200276), the Natural Science Foundation of Hubei Province, China (No. ZRMS2021000085), the Fundamental Research Funds for the Central Universities, China (No. 2021IVA039), the Open Foundation of State Key Laboratory of Mineral Processing, BGRIMM Technology, China (Nos. BGRIMM-KJSKL-2021-22 and BGRIMM-KJSKL-2022-02), and the Open Project of Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, China (No. 201904).
Publisher
EI Accession Number
20230513499274
EI Keywords
Adsorption ; Chemical bonds ; Esters ; Flotation ; Ilmenite ; Photoelectrons ; Photons ; Styrene ; X ray photoelectron spectroscopy ; Zeta potential
ESI Classification Code
Minerals:482.2 ; Electromagnetic Waves:711 ; Colloid Chemistry:801.3 ; Physical Chemistry:801.4 ; Chemical Operations:802.3 ; Organic Compounds:804.1 ; Probability Theory:922.1 ; Atomic and Molecular Physics:931.3 ; Quantum Theory; Quantum Mechanics:931.4
ESI Research Field
MATERIALS SCIENCE
Data Source
EV Compendex
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/519751
DepartmentAcademy for Advanced Interdisciplinary Studies
Affiliation
1.School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan; 430070, China
2.South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou; 510530, China
3.Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, Wuhan Institute of Technology, Wuhan; 430205, China
4.Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen; 518055, China
Recommended Citation
GB/T 7714
XU, Yan-ling,HUANG, Kai-hua,LI, Hong-qiang,et al. Adsorption mechanism of styryl phosphonate ester as collector in ilmenite flotation[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2022,32:4088-4098.
APA
XU, Yan-ling,HUANG, Kai-hua,LI, Hong-qiang,HUANG, Wei,LIU, Cheng,&YANG, Si-yuan.(2022).Adsorption mechanism of styryl phosphonate ester as collector in ilmenite flotation.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,32,4088-4098.
MLA
XU, Yan-ling,et al."Adsorption mechanism of styryl phosphonate ester as collector in ilmenite flotation".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 32(2022):4088-4098.
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