南方科技大学知识苑(SUSTech KC): Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents

Title	Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents
Author	Chen, Yang1,2,3 ; Chen, Weihao1,2,3 ; Gu, Xiao1,2,3 ; Ho, Chun-Yu1,2,3
Corresponding Author	Ho, Chun-Yu
Publication Years	2023-03-01
DOI	10.1055/s-0042-1751425
Source Title	SYNLETT Impact Factor & Quartile
ISSN	0936-5214
EISSN	1437-2096
Abstract	N-Heterocyclic carbene ligated transition-metal catalysts often show interesting properties and reactivity as compared to conventional ligand systems. In (NHC)Ni and (NHC)Pd hydrides, a dramatic reactivity changed from cross-hydroalkenylation to transfer-dehydroaromatization was observed under optimized conditions. This account summarizes our recent efforts and stories behind this serendipitous discovery. The mechanistic studies revealed that the keys to divert the desired reactivity are the differences in the olefin insertion selectivity and the hydrometallated species reactivity.
Keywords	hydroalkenylation transfer-hydrogenation dehydroaromatization N-heterocyclic carbenes nickel palladium
URL	[Source Record]
Indexed By	SCI
Language	English
SUSTech Authorship	First ; Corresponding
Funding Project	Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Southern University of Science and Technology (SUSTech)["Y01501808","Y01506014"] ; National Natural Science Foundation of China (NSFC)[22071096]
WOS Research Area	Chemistry
WOS Subject	Chemistry, Organic
WOS Accession No	WOS:000948838800003
Publisher	GEORG THIEME VERLAG KG
ESI Research Field	CHEMISTRY
Data Source	Web of Science
Citation statistics	Cited Times [WOS]:0
Document Type	Journal Article
Identifier	http://kc.sustech.edu.cn/handle/2SGJ60CL/523895
Department	Shenzhen Grubbs Institute 理学院_化学系
Affiliation	1.Southern Univ Sci &Technol SUSTech, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 2.Southern Univ Sci &Technol SUSTech, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci &Technol SUSTech, Dept Chem, Shenzhen 518055, Peoples R China
First Author Affilication	Southern University of Science and Technology; Shenzhen Grubbs Institute; Department of Chemistry
Corresponding Author Affilication	Southern University of Science and Technology; Shenzhen Grubbs Institute; Department of Chemistry
First Author's First Affilication	Southern University of Science and Technology
Recommended Citation GB/T 7714	Chen, Yang,Chen, Weihao,Gu, Xiao,et al. Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents[J]. SYNLETT,2023.
APA	Chen, Yang,Chen, Weihao,Gu, Xiao,&Ho, Chun-Yu.(2023).Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents.SYNLETT.
MLA	Chen, Yang,et al."Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents".SYNLETT (2023).

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