中文版 | English
Title

Self-Assembly Heterometallic Cu-Ln Complexes: Synthesis, Crystal Structures and Magnetic Characterization

Author
Corresponding AuthorZhang, Shaoliang; Wang, Yanlan; Li, Shanshan
Publication Years
2023-03-01
DOI
Source Title
EISSN
2073-4352
Volume13Issue:3
Abstract
Using N2O4 donor symmetric ligand H2L and dca co-ligand, two new isostructural dinuclear Cu-II-Ln(III) complexes [Cu(Cl)(L)Ln(NO3)(CH3OH)(H2O)(dca)] [Ln=Ho (1(CuHo)), Gd (2(CuGd))] [H2L = 6,6 '-((1E,1 ' E)-(ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol); dca=dicyanamide] were designed, synthesized and studied. In the two isostructural compounds, the geometric environment around the nine-coordinated Ln(III) ions is muffin, whereas the geometry of the penta-coordinated Cu(II) ions is square pyramid. The magnetic properties of both complexes were also studied. Direct current magnetic susceptibility measurements indicate ferromagnetic interactions between the Cu(II) ion and Gd(III) ion in complex 2(Cu)(Gd). Alternating current (ac) magnetic measurements indicate that complex 1(Cu)(Ho) displays slow magnetic relaxation behaviour.
Keywords
URL[Source Record]
Indexed By
Language
English
SUSTech Authorship
Others
WOS Research Area
Crystallography ; Materials Science
WOS Subject
Crystallography ; Materials Science, Multidisciplinary
WOS Accession No
WOS:000955995500001
Publisher
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/523935
DepartmentDepartment of Chemistry
Affiliation
1.Liaocheng Univ, Inst Funct Organ Mol & Mat, Sch Chem & Chem Engn, Liaocheng 252059, Peoples R China
2.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Peoples R China
3.Liaocheng Univ, Sch Geog & Environm, Liaocheng 252059, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Shaoliang,Du, Ruili,Fan, Xiufang,et al. Self-Assembly Heterometallic Cu-Ln Complexes: Synthesis, Crystal Structures and Magnetic Characterization[J]. CRYSTALS,2023,13(3).
APA
Zhang, Shaoliang,Du, Ruili,Fan, Xiufang,Zhao, Xinhua,Wang, Yanlan,&Li, Shanshan.(2023).Self-Assembly Heterometallic Cu-Ln Complexes: Synthesis, Crystal Structures and Magnetic Characterization.CRYSTALS,13(3).
MLA
Zhang, Shaoliang,et al."Self-Assembly Heterometallic Cu-Ln Complexes: Synthesis, Crystal Structures and Magnetic Characterization".CRYSTALS 13.3(2023).
Files in This Item:
There are no files associated with this item.
Related Services
Fulltext link
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Export to Excel
Export to Csv
Altmetrics Score
Google Scholar
Similar articles in Google Scholar
[Zhang, Shaoliang]'s Articles
[Du, Ruili]'s Articles
[Fan, Xiufang]'s Articles
Baidu Scholar
Similar articles in Baidu Scholar
[Zhang, Shaoliang]'s Articles
[Du, Ruili]'s Articles
[Fan, Xiufang]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Shaoliang]'s Articles
[Du, Ruili]'s Articles
[Fan, Xiufang]'s Articles
Terms of Use
No data!
Social Bookmark/Share
No comment.

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.