中文版 | English
Title

Hetero-carbolong chemistry: experimental and theoretical studies of diaza-metallapentalenes

Author
Corresponding AuthorChen, Dafa; Xia, Haiping
Publication Years
2023-03-01
DOI
Source Title
ISSN
1359-7345
EISSN
1364-548X
Abstract
Four diaza-osmapentalenes were prepared by two-step reactions, through the treatment of an alkyne-coordinated osmium complex with azo compounds, followed by the addition of AgSbF6/CO. Their aromaticity was confirmed by crystal parameters, NMR spectra and theoretical calculations. These complexes are the first diaza-metallapentalenes representing a new class of metallaaromatics.
URL[Source Record]
Indexed By
Language
English
SUSTech Authorship
Corresponding
Funding Project
NSFC["22071098","21931002","92156021","22101115"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Shenzhen Science and Technology Innovation Committee["JCYJ20210324105013035","JCYJ20200109140812302"]
WOS Research Area
Chemistry
WOS Subject
Chemistry, Multidisciplinary
WOS Accession No
WOS:000953632600001
Publisher
ESI Research Field
CHEMISTRY
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:0
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/523951
DepartmentShenzhen Grubbs Institute
理学院_化学系
Affiliation
1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China
Corresponding Author AffilicationShenzhen Grubbs Institute
Recommended Citation
GB/T 7714
Chu, Zhenwei,Li, Jinhua,Hua, Yuhui,et al. Hetero-carbolong chemistry: experimental and theoretical studies of diaza-metallapentalenes[J]. CHEMICAL COMMUNICATIONS,2023.
APA
Chu, Zhenwei,Li, Jinhua,Hua, Yuhui,Luo, Ming,Chen, Dafa,&Xia, Haiping.(2023).Hetero-carbolong chemistry: experimental and theoretical studies of diaza-metallapentalenes.CHEMICAL COMMUNICATIONS.
MLA
Chu, Zhenwei,et al."Hetero-carbolong chemistry: experimental and theoretical studies of diaza-metallapentalenes".CHEMICAL COMMUNICATIONS (2023).
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