| Title | Copper-catalyzed radical trifluoromethylalkynylation of unactivated alkenes with terminal alkynes |
| Author | |
| Corresponding Author | Liu, Lin; Liu, Xin-Yuan |
| Publication Years | 2023-04-01
|
| DOI | |
| Source Title | |
| ISSN | 0022-1139
|
| EISSN | 1873-3328
|
| Volume | 267 |
| Abstract | A copper-catalyzed three-component radical trifluoromethylalkynylation of unactivated alkenes is realized from Togni-II reagent and readily available terminal alkynes under mild conditions to afford an array of beta-tri- fluoromethylated alkynes. The utilization of a multidentate N,N,N-ligand is crucial for the efficient radical generation and the C(sp3)-C(sp) bond formation. Facile transformations of the difunctionalization products highlight its potential utility in the synthesis of various trifluoromethyl-containing building blocks. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | Corresponding
|
| Funding Project | National Key R & D Program of China["2021YFF0701704","2021YFF0701604"]
; National Natural Science Foundation of China["22025103","92256301","21831002","22201127","22101122"]
; Guangdong Innovative Program[2019BT02Y335]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
; Shenzhen Science and Technology Program["KQTD20210811090112004","JCYJ20220818100604009","JCYJ20200109141001789"]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Inorganic & Nuclear
; Chemistry, Organic
|
| WOS Accession No | WOS:000956028500001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/524030 |
| Department | Shenzhen Grubbs Institute 前沿与交叉科学研究院 理学院_化学系 |
| Affiliation | 1.Great Bay Univ, Inst Sci Res, Sch Sci, Dongguan 523000, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 4.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China 5.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
| First Author Affilication | Shenzhen Grubbs Institute; Department of Chemistry |
| Corresponding Author Affilication | Shenzhen Grubbs Institute; Department of Chemistry |
| Recommended Citation GB/T 7714 |
Ren, Yang-Qing,Yang, Chang-Jiang,Li, Zhong-Liang,et al. Copper-catalyzed radical trifluoromethylalkynylation of unactivated alkenes with terminal alkynes[J]. JOURNAL OF FLUORINE CHEMISTRY,2023,267.
|
| APA |
Ren, Yang-Qing,Yang, Chang-Jiang,Li, Zhong-Liang,Gu, Qiang-Shuai,Liu, Lin,&Liu, Xin-Yuan.(2023).Copper-catalyzed radical trifluoromethylalkynylation of unactivated alkenes with terminal alkynes.JOURNAL OF FLUORINE CHEMISTRY,267.
|
| MLA |
Ren, Yang-Qing,et al."Copper-catalyzed radical trifluoromethylalkynylation of unactivated alkenes with terminal alkynes".JOURNAL OF FLUORINE CHEMISTRY 267(2023).
|
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
;
Edit Comment