| Title | Kinetics of the Simplest Criegee Intermediate CH2OO Reaction with tert-Butylamine |
| Author | |
| Corresponding Author | Dong, Wenrui |
| Publication Years | 2023-03-23
|
| DOI | |
| Source Title | |
| ISSN | 1089-5639
|
| EISSN | 1520-5215
|
| Volume | 127Issue:11 |
| Abstract | The kinetics of the simplest Criegee intermediate (CH2OO) reaction with tert-butylamine ((CH3)3CNH2) was studied under pseudo-first -order conditions with the OH laser-induced fluorescence (LIF) method at the temperature range of 283???318 K and the pressure range of 5???75 Torr. Our pressure-dependent measurement showed that at 5 Torr-the lowest pressure measured in the current experiment -this reaction was under the high-pressure limit condition. At 298 K, the reaction rate coefficient was measured to be (4.95 ?? 0.64) ?? 10???12 cm3 molecule???1 s???1. The title reaction was observed to be negative temperature-dependent; the activation energy of (???2.82 ?? 0.37) kcal mol???1 and the pre-exponential factor of (4.21 ?? 0.55) ?? 10???14 cm3 molecule???1 s???1 were derived from the Arrhenius equation. The rate coefficient of the title reaction is slightly larger than (4.3 ?? 0.5) ?? 10???12 cm3 molecule???1 s???1 of the CH2OO reaction with methylamine; the electron inductive effect and the steric hindrance effect might play a role in contributing to such difference. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | Others
|
| Funding Project | National Natural Science Foundation of China["21873098","22288201"]
; Chinese Academy of Sciences[GJJSTD20220001]
; Liaoning Revitalization TalentsProgram[XLYC1807248]
; Innovation Program for Quantum Science and Technology[2021ZD0303305]
|
| WOS Research Area | Chemistry
; Physics
|
| WOS Subject | Chemistry, Physical
; Physics, Atomic, Molecular & Chemical
|
| WOS Accession No | WOS:000953984100001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/524058 |
| Department | Department of Chemistry |
| Affiliation | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Chem Lasers, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 4.Univ Sci & Technol China, Sch Chem & Mat Sci, Dept Chem Phys, Hefei 230026, Peoples R China 5.Dalian Univ Technol, Sch Phys, Key Lab Mat Modificat Laser Ion & Electron Beams, Chinese Minist Educ, Dalian 116024, Peoples R China 6.Dalian Maritime Univ, Dept Phys, Dalian 116026, Liaoning, Peoples R China 7.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
| Recommended Citation GB/T 7714 |
Chen, Yang,Jiang, Haotian,Liu, Siyue,et al. Kinetics of the Simplest Criegee Intermediate CH2OO Reaction with tert-Butylamine[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2023,127(11).
|
| APA |
Chen, Yang.,Jiang, Haotian.,Liu, Siyue.,Shi, Jiayu.,Jin, Yuqi.,...&Dong, Wenrui.(2023).Kinetics of the Simplest Criegee Intermediate CH2OO Reaction with tert-Butylamine.JOURNAL OF PHYSICAL CHEMISTRY A,127(11).
|
| MLA |
Chen, Yang,et al."Kinetics of the Simplest Criegee Intermediate CH2OO Reaction with tert-Butylamine".JOURNAL OF PHYSICAL CHEMISTRY A 127.11(2023).
|
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