中文版 | English
Title

Photochemical C––H Bond Activation by Gold, Platinum, Tungsten, and Osmium Complexes

Author
Corresponding AuthorChi-Ming Che
Publication Years
2022-11-29
ISBN
9783527834242
Source Title
Publication Place
美国
Publisher
Abstract

To meet the increasing demand for environmentally benign and sustainable chemical processes, the use of light in organic synthesis is blossoming. Over the past decades, luminescent transition metal complexes have been extensively studied as photosensitizers due to their excellent photophysical properties and flexibility in structure modification. The visible-light photo-catalysis has been developed rapidly, from “proof of concept” to “a useful strategy,” in a broad range of organic transformation reactions that can be used in practical organic synthesis. Compared with the extensive literatures on ruthenium and iridium complexes used in visible-light catalysis, the summaries on gold, platinum tungsten (except polyoxotungstates), and osmium complexes catalyzed photochemical reactions are scarce. In this article, the recent developments in photochemical reactions catalyzed by gold (Au), platinum (Pt), tungsten (W), and osmium (Os) complexes, as well as the mechanistic studies and their applications in organic synthesis are summarized. The photochemical reactions discussed herein mainly refer to the ones with transition metal complexes that absorb light in the UV–visible spectral region and which serve as a photo-redox catalyst or a photosensitizer.

DOI
Language
English
Data Source
人工提交
Citation statistics
Cited Times [WOS]:0
Document TypeBook chapter
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/527473
DepartmentDepartment of Chemistry
Affiliation
Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong, China
First Author AffilicationDepartment of Chemistry
Corresponding Author AffilicationDepartment of Chemistry
Recommended Citation
GB/T 7714
Yungen Liu,Hao-Chong Tan,Daohong Yu,等. Photochemical C––H Bond Activation by Gold, Platinum, Tungsten, and Osmium Complexes. 美国:WILEY-VCH GmbH,2022.
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