| Title | 一种可光催化苄胺氧化偶联制备亚胺的CCC型三齿铱配合物 |
| Alternative Title | CCC type tridentate iridium complex capable of preparing imine through oxidative coupling of benzylamine under photocatalysis
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| Author | |
| First Inventor | 夏海平
|
| Original applicant | 南方科技大学
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| First applicant | 南方科技大学
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| Address of First applicant | 518000 广东省深圳市南山区学苑大道1088号
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| Current applicant | 南方科技大学
|
| Address of Current applicant | 518000 广东省深圳市南山区学苑大道1088号 (广东,深圳,南山区)
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| First Current Applicant | 南方科技大学
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| Address of First Current Applicant | 518000 广东省深圳市南山区学苑大道1088号 (广东,深圳,南山区)
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| Application Number | CN202210935679.8
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| Application Date | 2022-08-04
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| Open (Notice) Number | CN115260251A
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| Date Available | 2022-11-01
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| Status of Patent | 实质审查
|
| Legal Date | 2022-11-18
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| Subtype | 发明申请
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| SUSTech Authorship | First
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| Abstract | 本发明涉及金属有机化学领域和配位化学，公开一种CCC型三齿铱配合物及其制备方法和应用。其合成方法是以多炔碳链为起始原料，与[Ir(CH3CN)(CO)(PPh3)2][BF4]反应，得到铱配合物1，然后在HBF4·H2O条件下脱水得到铱配合物2，最后与甲醇反应得到铱配合物3。本发明CCC型三齿铱配合物可应用于高效催化苄胺的氧化偶联反应制备亚胺，具有产物收率高，经济环保等特点。 |
| Other Abstract | The invention relates to the field of metal organic chemistry and coordination chemistry, and discloses a CCC type tridentate iridium complex as well as a preparation method and application thereof. The synthesis method comprises the following steps: taking a polyacetylene carbon chain as an initial raw material, reacting with [Ir (CH3CN) (CO) (PPh3) 2] [BF4] to obtain an iridium complex 1, then dehydrating under the condition of HBF4.H2O to obtain an iridium complex 2, and finally reacting with methanol to obtain an iridium complex 3. The CCC type tridentate iridium complex can be used for preparing imine by efficiently catalyzing oxidative coupling reaction of benzylamine, and has the characteristics of high product yield, economy, environmental protection and the like. |
| IPC Classification Number | C07F15/00
; B01J31/24
; C07C249/02
; C07C251/24
|
| INPADOC Legal Status | （ENTRY INTO FORCE OF REQUEST FOR SUBSTANTIVE EXAMINATION）[2022-11-18][CN]
|
| INPADOC Patent Family Count | 1
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| Extended Patent Family Count | 1
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| Priority date | 2022-08-04
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| Patent Agent | 江丽娇
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| Agency | 广东金泰智汇专利商标代理事务所(普通合伙)
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| URL | [Source Record] |
| Data Source | PatSnap
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| Document Type | Patent |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/531910 |
| Department | Department of Chemistry 深圳格拉布斯研究院 |
| Recommended Citation GB/T 7714 |
夏海平,陈大发,李金华,等. 一种可光催化苄胺氧化偶联制备亚胺的CCC型三齿铱配合物.
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